We need to create a Functional Model of IC Interconnection to understand and learn the functional and problem ranks of all components.
We will take one metal layer created above the layer below.
The purpose of the IC interconnection is to electrically connect the metal in the layer below to the metal line above. Therefore, the system's product would be Current.
The challenges are as follows:
We need a dielectric material (ILD) to be able to keep the metal line mechanically and separated electrically
ILD - Interlayer dielectric that is typically built of SiO2 or modified SiO2
The metal lines and via are made from Cu
Cu diffuses through the ILD, resulting in shortening - the creation of electrical contacts through ILD
The barrier (typically Ta) is used for preventing Cu diffusion into ILD within the layer
Etch stop layer (typically Si3N4, SiC) aims to prevent Cu diffusion to ILD on the upper layer
Cu is affected by the electromigration effect; therefore, the bottom Barrier that separates the top of the via from the metal at the low layer helps to prevent the formation of huge voids due to Cu electromigration from layer to layer
During the Functional Modeling, we need to take into account the RC-delay that affects the signal and should be as low as possible. RC-delay = R X C where R is the total resistivity of metal layers, and Vias and C is the total capacitance of vertical and horizontal gaps of dielectrics located between metal lines. The resistivity of the metal lines and metal vias should be as low as possible; the Dielectric permittivity of dielectric layers should be as low as possible.
The interconnection part is shown below:
Let's start to create a Functional Model.
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Ineffective
Basic functions
Components
Supersystems
Barrier - top layer | 10 10 |
ILD - top layer | 8 2.2 |
Cu metal - top layer | 5 1.3 |
Metal - bottom layer | 5 |
Cu via - top layer | 3 1 |
ILD - bottom layer | 2 |
Etch stop layer | 2 |
Barrier - bottom layer | 2 0.7 |
Cu - diffusion | 0.8 |
Cu electromigration voids | 5 |
Exciting result - the most functional component for current providing is not a metal line but a component that keeps the metal line:
The conclusion - the carrier has higher functionality than the metal line that provides electrical current.
So, we need to think about how to eliminate barriers and delegate its functions to another component - small air gaps between Cu metal lines and ILD seem to be very perspective from the standpoint of both Cu diffusion prevention and RC-delay reduction
The possible configuration can be as shown below:
The Functional Model is in the Proposed Version
The Air Gaps model seems much better and also helps to prevent void formation due to Cu electromigration - the void already exists. It might happen that due to very strong Cu-electromigration, the shape of the via and metal line will be slightly affected, but no voids will be created within the metal line or within the metal via.
If | Barrier - top layer remains unchanged |
---|---|
Then | Barrier - top layer Keeps Cu metal - top layer |
But | Barrier - top layer Reduces Cu metal - top layer |
The next step is to analyze the manufacturing process of the IC interconnection layer.
Generally, we need to process the structure:
To the structure:
Let's analyze all the steps needed to make an additional interconnection layer. We will use very general operations of the typical process used in many fabs for manufacturing BEOL layers.
Let's start, go to the "Model"
We need to complete 13 sequential operations to create a metal layer.
Generally speaking, two types of operations in semiconductor manufacturing aim to either deposit something or remove something.
A typical reasonable process flow is shown below:
After the photolithography operation, the pattern resist is tested with metrological operation (that is not shown in the flow). During the pattern measurements, the critical parameters are measured - Critical Dimensions Measurements (CDM) - size, location, thickness etc. The measurements are invasive therefore, the measurements are performed on the special metrocell and not on the die.
Defect metrology operation is placed after Step 11 - Barrier + Cu-seed deposition - not shown in the flow but will be analyzed in the process flow analysis.
Let's analyze the process using Process Functional Modeling, a creative thinking tool. No metrology operations were taken into account. Go to "Model"
Step 1 Etch Stop Deposition
Step 2 ILD Deposition
Step 3 Sacrificial Layer Deposition for Via
Step 4 Photolithography patterning for Via
Step 4 M - Critical Dimensions Measurements (CDM) - Via
Step 5 Via Etch
Step 6 Wet Cleaning after Via Etch
Step 7 Sacrificial Layer Deposition for Trench
Step 8 Photolithography Patterning for Trench
Step 8 M - Critical Dimensions Measurements (CDM) - Trench
Step 9 Trench Etch for Metal Line
Step 10 Wet Cleaning after Trench Etch
Step 11 Ta-Barrier + Cu-Seed layers Deposition
Step 11 M - Defects Detection & Measurements
Step 12 Cu Electroplating
Step 13 Excessive Cu and Barrier Removal by Polish
Effective
Ineffective
Productive
Providing
Corrective
Metrology
Operation Type | Does it increase cost? | Does it increase product value? | Recommendation |
---|---|---|---|
Productive | Yes | Yes | Improve |
Providing | Yes | No | Eliminate |
Corrective | Yes | No | Eliminate |
Metrology | Yes | No | Eliminate |
Operation | Type | Merit | Recommendation |
---|---|---|---|
Step 1 Etch Stop Deposition | Productive | OE 1.51 | Consider improving |
Step 2 ILD Deposition | Productive | OE 2.57 | Consider improving |
Step 3 Sacrificial Layer Deposition for Via | Providing | OE 1.35 | Consider eliminating |
Step 4 Photolithography patterning for Via | Providing | OE 4.01 | Consider eliminating |
Step 4 M - Critical Dimensions Measurements (CDM) - Via | Metrology | OE 1.9 | Consider the necessity of the information and eliminate it when possible |
Step 5 Via Etch | Productive | OE 2.88 | Consider improving |
Step 6 Wet Cleaning after Via Etch | Corrective | OE 2.4 | Do nothing and eliminate it when possible |
Step 7 Sacrificial Layer Deposition for Trench | Providing | OE 1.35 | Consider eliminating |
Step 8 Photolithography Patterning for Trench | Providing | OE 4.01 | Consider eliminating |
Step 8 M - Critical Dimensions Measurements (CDM) - Trench | Metrology | OE 1.9 | Consider the necessity of the information and eliminate it when possible |
Step 9 Trench Etch for Metal Line | Productive | OE 2.88 | Consider improving |
Step 10 Wet Cleaning after Trench Etch | Corrective | OE 2.4 | Do nothing and eliminate it when possible |
Step 11 Ta-Barrier + Cu-Seed layers Deposition | Providing | OE 2.47 | Consider eliminating |
Step 11 M - Defects Detection & Measurements | Metrology | OE 2.29 | Consider the necessity of the information and eliminate it when possible |
Step 12 Cu Electroplating | Productive | OE 1.65 | Consider improving |
Step 13 Excessive Cu and Barrier Removal by Polish | Corrective | OE 1.38 | Do nothing and eliminate it when possible |
Summary of the process functional modeling:
Some directions for the process development:
1 Step is the transformation from the structure:
To the structure:
The Etch Stop layer is mainly needed to preserve the Cu diffusion to the ILD of the top layer - the top barrier. It is typically made of Si3N4 or SiC because increased density is needed to ensure barrier properties against Cu diffusion.
The Etch Stop layer deposition is usually performed by the CVD method.
The operation aims to create the Etch Stop layer therefore, the product is the "Etch Stop Layer"
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Basic functions
Components
Supersystems
Plasma | 10 |
CVD system | 5.5 |
Initial layer | 4 |
Gaseous Chemicals | 3.5 |
Wafer | 3 |
Cu - Initial layer | 2.5 |
ILD - Initial layer | 2.5 |
Chuck | 2 |
Vacuum pump | 10 |
By-product gases | 2.6 |
Air | 9.2 |
It is exciting results:
Plasma is the most functional component - we have to think about plasma for effective improvement of the process
The vacuum pump came out as the most problematic component of the system - we have to think about how to eliminate or replace the vacuum pump - Interesting.
Overall:
Etch stop Deposition is not a valuable operation. The operation's main purpose is to create a barrier between the Cu metal line and the top of ILD. Actually, we cover the surface of the wafer with Etch stop material, while we need it only on the top of Cu metal line.
Maybe we need to think about the material that is adsorbed bu Cu only and is not adsorbed by SiO2 - ILD. The process could be done as follows: spinon liquid, removing the liquid from the wafer at high-speed rotation (the liquid should remain only on the metallic parts), and thermal treatment of the liquid to create a top barrier layer.
So we need to develop a liquid that is adsorbed selectively by Cu and is converted to solid material after a thermal treatment.
Possible example:
A suitable liquid material that selectively adsorbs on Cu and converts to a solid after thermal treatment is Poly(methyl methacrylate) (PMMA) in a suitable solvent. Here’s how it works:
This approach allows for effective selective adsorption and subsequent solidification, making it suitable for applications in wafer fabrication.
2 Step is the deposition of the ILD layer - a transformation from structure:
To structure:
ILD is typically built of SiO2 or modified SiO2 for the reduction of dielectric permittivity. The Electric permittivity reduction is typically achieved by the creation pores and dipping with C (in the form of methyl), Fluorine
ILD deposition is typically made by the CVD process, where gaseous components are converted into a thin solid film due to the process in plasma.
The operation aims to deposit ILD; therefore, the product (target) of the step is ILD.
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Basic functions
Components
Supersystems
Plasma | 10 |
Gaseous chemicals | 4 |
Etch Stop layer | 4 |
CVD Tool | 4 |
Previous layers | 2.7 |
Air residue | 2.7 10 |
Vacuum pump | 2 2 |
Wafer | 2 |
Chuck | 1.3 |
Gaseous by-products | 0.7 |
Stupid question. Why do we need a vacuum for ILD deposition? I see only one possible reason - to create a free pathway that is long enough for plasma creation. OK. We need to think about how to ensure plasma and avoid deep vacuum. ILD that is SiO2 or modifications of SiO2 do not need a vacuum. More than that, the lack of oxygen
3 Step is the deposition of the Sacrificial light-absorbing Layer (SLAL). The main purpose of this layer is to absorb the light during Photolithography and prevent the formation of a standing wave due to the interference of initial reflected light.
The structure:
Should be converted to the structure:
The layer is typically deposited by a spin-on procedure similar to the deposition of a photoresist.
The operation aims to deposit SLAL; therefore, the product (target) of the operation is SLAL.
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Basic functions
Components
Supersystems
Chamber for Spin on | 10 |
ILD layer | 5 |
Furnace | 5 |
Liquid material for
Spin on deposition | 5 |
Chuck | 4 |
Air Fan | 4 |
Air | 3 |
Nozzle for
liquid material | 3 |
Wafer | 3 |
Exhaust | 2 |
Air Filter | 7.5 |
Vapor of the
liquid material | 10 |
Vapors of solid
sacrificial material | 10 |
Particles | 5 |
There are too many components. It would be easier and more effective to use hot air to solidify the Sacrificial Light Absorbing Material when it is on the wafer. So, the process seems to be like this: Wafer is kept in the chuck and rotated. The liquid stuff is poured on the rated wafer, and hot air solidifies the material on the wafer. The local flow of the air will preserve the wafer from the contamination of the layer. A chamber filter and Fan will not be needed.
4th Step is the wafer patterning using Photolithography (PL). PL is a preparation for the next step, which is Dry Etch (Plasma Etch). The purpose of the operation is to deposit the Photo Resist (PR) and create a pattern: the areas that are covered with the PR will not be affected by the Plasma etch, and opened areas will be etched by plasma.
Incoming structure:
Outcoming structure after the PL process should be as follows:
This step creates the pattern for Via etch only. The PL process generally consists of three sequential parts: deposition of the Photo Resist (PR), Exposure - optical exposing of the PR through the special mask, and Development - chemical removal of the exposed part of the PR; unexposed parts will remain on the wafer. (In the case of "negative resist, "the effect is the opposite - exposed parts will remain, while unexposed parts will be removed at the development).
The operation aims to create a patterned photoresist; therefore, its product (target) is Via Patterned PR.
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Basic functions
Components
Supersystems
Exposed PR | 10 10 |
Liquid Developer | 10 |
Scanner | 7.5 |
Wafer | 5.8 |
Oven | 5.8 |
Liquid PR | 5.8 5.8 |
Sacrificial Light
Absorbing Layer | 5 5 |
Solid PR | 4.2 |
Development Chamber | 4.2 |
Dev Nozzle | 4.2 |
Exposure Chamber | 4.2 |
Chuck for
Spin on | 3.3 |
Liquid PR layer | 3.3 |
PR Spin on
Chamber | 2.5 |
Nozzle for
liquid PR | 2.5 |
Dev Chuck | 1.7 |
Exposure Chuck | 1.7 |
ILD layer | 1.7 |
Photolithography does not add value to the product. The PL operation is very complex, so there is no reason to develop the operation and equipment. The PL operation is very expensive and must be simplified and eliminated.
The Exposed Resist is the most functional component. So, let's document some ideas for simplification of the PL process:
Critical Dimensions Measurements (CDM) are performed after Photolithography. The main parameters of the photoresist pattern are measured and collected to decide whether to continue the wafer's process or return to the rework. The measurements are invasive, so they cannot be done on the die; they are performed on the scribe line between the dies on the specially created metro cell. Every single measurement is performed on the new metro cell because the measurements destroy the metro cell. The fragment of the typical pattern is shown below.
The main purpose of the CDM operation is the information, Product is Information.
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Basic functions
Components
Supersystems
Metrology tool | 10 10 |
Patterned Photoresist | 4 |
Metro Cell | 3 |
Wafer | 2 |
The operation does not increase the product's value and only gives data to decide on the necessity of rework. The best way is to analyze the statistics and insert a reasonable skip of the operation. The criteria should be the ratio: "Gain/Cost" .
5th Step is to etch a Via according to the pattern that was made at the previous step - Via Photo Lithography. The etch is performed with plasma on the all surface of the wafer. The open parts will be etched, while the parts that are covered with the Photoresist (PR) will remain unchanged. The wafer is placed on the chuck, kept with static electricity and treated with plasma containing the ions and/or radicals to be able to convert the ILD in to the gas. Typically, the plasma contains fluorine that converts silicon oxide to gaseous silicon tetrafluoride.
Incoming structure:
Outcoming structure:
This step is a productive operation that provides irreversible changes and increases the value of the product.
The operation aims to create a Via within the ILD according to the patterned resist on the wafer. A via is created due to the conversion of SiO2 of ILD into gaseous SiF4, therefore, its product (target) is a SiF4 - gas.
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Basic functions
Components
Supersystems
Fluorine ions | 10 |
Etch stop Layer | 8.9 |
Plasma | 6.7 3.9 |
ILD | 6.7 |
Pump | 5.6 10 |
Photoresist | 5.6 |
Electromagnetic field | 5.6 |
Sacrificial light
absorbing layer | 2.2 1.7 |
Residual gases | 2.2 |
The vacuum pump seems to be the most problematic component of the system. The pump is used to create a vacuum in the chamber to ensure a long enough free path for the ions and radicles. At the same time, the pump should remove the etch product - SiF4 gas. The problem is the SiF4 gas may not be removed effectively because of the high vacuum. Excessing SiF4 reduces the etch rate and can result in the under etch. SiF4 and other gaseous by-products should be pumped out properly and fast to ensure a high and stable etch rate of the process.
One of the possible solutions that came out of the 40 Inventive Principles analysis is to make the Dry etch process in pulses to allow better pumping out of the SiF4 and all other gaseous by-products.
Wet cleaning is typically performed after the Dry etch process to remove the residual photoresist and sacrificial light-absorbing material and to clean the via from the by-products formed during the Dry etch process—the interaction of plasma with pattern and ILD.
The incoming structure is shown below:
The outcoming structure should look as follows:
The purpose of the operation is to remove the temporary pattern. So, the product (target) of the operation Residue.
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Basic functions
Components
Supersystems
Cleaning solution | 10 10 |
Chuck | 7.5 |
Wet Cleaning system | 5 |
Dissolved Residue | 5 2.5 |
Nozzle | 2.5 |
It is interesting that "Chuck" becomes a component with relatively high functionality. It occurs because it is important to dissolve the residue, but we also need to remove the dissolved residue; otherwise, the residue will remain on the wafer. The removal of the dissolved residue becomes very important.
From 40 inventive principles, we generated an idea to invert the process. Instead of pouring the chemistry on the rotating wafer, we can dip the rotating wafer face down into the solution in the bath.
Another direction for development and real innovation is to remove the residue at the previous operation - dry etch. In this case, the Wet etch operation will not be necessary and can be eliminated.
The seventh step is depositing the Sacrificial light-absorbing Layer (SLAL). This layer has two purposes: to fill in the via and avoid unnecessary etching within it, to absorb light during photolithography, and to prevent the formation of a standing wave due to the interference of initial reflected light.
The initial structure:
Should be converted to the structure:
The layer is typically deposited by a spin-on procedure similar to the deposition of a photoresist.
The operation aims to deposit SLAL; therefore, the product (target) of the operation is SLAL.
Effective
Ineffective
Basic functions
Components
Supersystems
Chamber for Spin on | 10 |
ILD layer | 5 |
Furnace | 5 |
Liquid material for
Spin on deposition | 5 |
Chuck | 4 |
Air Fan | 4 |
Air | 3 |
Nozzle for
liquid material | 3 |
Wafer | 3 |
Exhaust | 2 |
Air Filter | 7.5 |
Vapor of the
liquid material | 10 |
Vapors of solid
sacrificial material | 10 |
Particles | 5 |
Same as the Step 3 - Sacrificial Layer Deposition for Via
There are too many components. It would be easier and more effective to use hot air to solidify the Sacrificial LigLight-Absorbing Material the wafer. So, the process seems to be like this: WafThe wafer is kept in the chuck and rotated. The liquid is poured onto a rated wafer, and hot air solidifies the material on the wafer. The local flow of the air will preserve the wafer from contamination by layer. A chamber filter and Fan will not be needed.
The eighth 8 step is wafer patterning using Photolithography (PL). PL prepares the wafer for the next step, Dry Etch (Plasma Etch). The operation deposits the Photo Resist (PR) and creates a pattern: areas covered with PR are not affected by the Plasma etch, and opened areas are etched by plasma. This operation is for Trench patterning.
Incoming structure:
Outcoming structure after the PL process should be as follows:
This step creates the pattern for Trench etch only. The PL process generally consists of three sequential parts: deposition of the Photo Resist (PR), Exposure - optical exposing of the PR through the special mask, and Development - chemical removal of the exposed part of the PR; unexposed parts will remain on the wafer. (In the case of "negative resist, "the effect is the opposite - exposed parts will remain, while unexposed parts will be removed at the development).
The operation aims to create a patterned photoresist, so its product (target) is Trench-Patterned PR.
Effective
Ineffective
Basic functions
Components
Supersystems
Exposed PR | 10 10 |
Liquid Developer | 10 |
Scanner | 7.5 |
Wafer | 5.8 |
Oven | 5.8 |
Liquid PR | 5.8 5.8 |
Sacrificial Light
Absorbing Layer | 5 5 |
Solid PR | 4.2 |
Development Chamber | 4.2 |
Dev Nozzle | 4.2 |
Exposure Chamber | 4.2 |
Chuck for
Spin on | 3.3 |
Liquid PR layer | 3.3 |
PR Spin on
Chamber | 2.5 |
Nozzle for
liquid PR | 2.5 |
Dev Chuck | 1.7 |
Exposure Chuck | 1.7 |
ILD layer | 1.7 |
Photolithography does not add value to the product. The PL operation is very complex, so there is no reason to develop the operation and equipment. The PL operation is very expensive and must be simplified and eliminated.
The Exposed Resist is the most functional component. So, let's document some ideas for simplification of the PL process:
Critical Dimensions Measurements (CDM) are performed after Photolithography. The main parameters of the photoresist pattern are measured and collected to decide whether to continue the wafer's process or return to the rework. Because the measurements are invasive, they cannot be performed on the die; they are performed on the scribe line between the dies on the specially created metro cell. Every single measurement is performed on the new metro cell because they destroy the metro cell. The fragment of the typical pattern is shown below.
The structure that is submitted to CDM:
The main purpose of the CDM operation is the information, Product is Information.
Effective
Ineffective
Basic functions
Components
Supersystems
Metrology tool | 10 10 |
Patterned Photoresist | 4 |
Metro Cell | 3 |
Wafer | 2 |
The operation does not increase the product's value and only gives data to decide on the necessity of rework. The best way is to analyze the statistics and insert a reasonable skip of the operation. The criteria should be the ratio: "Gain/Cost" .
9th Step is to etch a Trench for metal wires according to the pattern made at the previous step - Trench Photo Lithography. The etch is performed with plasma on the complete surface of the wafer. The open parts will be etched, while the parts covered with the Photoresist (PR) will remain unchanged. The wafer is placed on the chuck, kept with static electricity and treated with plasma containing the ions and/or radicals to be able to convert the ILD in to the gas. Typically, the plasma contains fluorine that converts silicon oxide to gaseous silicon tetrafluoride.
Incoming structure:
Outcoming structure:
This step is a productive operation that provides irreversible changes and increases the value of the product.
The operation aims to create a Via within the ILD according to the patterned resist on the wafer. A via is created due to the conversion of SiO2 of ILD into gaseous SiF4; therefore, its product (target) is a SiF4 - gas.
Effective
Ineffective
Basic functions
Components
Supersystems
Fluorine ions | 10 |
Etch stop Layer | 8.9 |
Plasma | 6.7 3.9 |
ILD | 6.7 |
Pump | 5.6 10 |
Photoresist | 5.6 |
Electromagnetic field | 5.6 |
Sacrificial light
absorbing layer | 2.2 1.7 |
Residual gases | 2.2 |
The vacuum pump seems to be the most problematic component of the system. The pump is used to create a vacuum in the chamber to ensure a long enough free path for the ions and radicles. At the same time, the pump should remove the etch product - SiF4 gas. The problem is the SiF4 gas may not be removed effectively because of the high vacuum. Excessing SiF4 reduces the etch rate and can result in the under etch. SiF4 and other gaseous by-products should be pumped out properly and fast to ensure a high and stable etch rate of the process.
One of the possible solutions that came out of the 40 Inventive Principles analysis is to make the Dry etch process in pulses to allow better pumping out of the SiF4 and all other gaseous by-products.
Wet cleaning is typically performed after the Dry etch process to remove the residual photoresist and sacrificial light-absorbing material and to clean the via from the by-products formed during the Dry etch process—the interaction of plasma with pattern and ILD.
The incoming structure is shown below:
The outcoming structure should look as follows:
The purpose of the operation is to remove the temporary pattern. So, the product (target) of the operation Residue.
Effective
Ineffective
Basic functions
Components
Supersystems
Cleaning solution | 10 10 |
Chuck | 7.5 |
Wet Cleaning system | 5 |
Dissolved Residue | 5 2.5 |
Nozzle | 2.5 |
It is interesting that "Chuck" becomes a component with relatively high functionality. It occurs because it is important to dissolve the residue, but we also need to remove the dissolved residue; otherwise, the residue will remain on the wafer. The removal of the dissolved residue becomes very important.
From 40 inventive principles, we generated an idea to invert the process. Instead of pouring the chemistry on the rotating wafer, we can dip the rotating wafer face down into the solution in the bath.
Another direction for development and real innovation is to remove the residue at the previous operation - dry etch. In this case, the Wet etch operation will not be necessary and can be eliminated.
Step 11 is dedicated to depositing a thin layer of Tantalum (Ta) metal. Ta layer aims to prevent diffusion of copper (Cu) in the ILD, which is a silico-oxide-based dielectric material. Ta layer is a barrier between ILD and Cu. The operation's next step is disposing of a thin layer of Cu. This thin Cu layer aims to enable an electrical contact at the next operation - that is, electroplating - bulk Cu deposition by electrolysis. This thin Cu layer is named the Cu-seed layer because it allows the connection of the wafer to the Cathode and the electroplating process. Both Ta-barrier and Cu-seed layers are deposited using the PVD process - Physical Vapour Deposition. The plasma ions and radicles attract the target, which is made of relevant material - either Ta or Cu. The liberated metal aglomerates are deposited on the wafer surface, including the structure walls - vias and trenches of the metal lines.
The incoming structure is shown below:
The outcoming structure is shown below - Ta-barrier and Cu-seed layers are shown as a single black line:
The purpose of the operation is to deposit a Ta-barrier and Cu-seed layer. The Cu-seed layer is deposited on the top of the Ta-barrier layer; therefore, we can assign the Cu-seed layer as a product (target) of the operation.
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Basic functions
Components
Supersystems
Ions & radicles | 10 4.4 |
Electromagnetic field | 7.5 |
Ta - barrier layer | 5 |
Cu agglomerates | 3.1 |
Wafer | 3.1 |
Ta agglomerates | 1.9 |
Process gas | 1.9 |
Cu - target | 1.9 |
Ta - target | 1.3 |
Chuck | 1.3 |
Vacuum pump | 1.3 1.1 |
Air | 10 |
Step 11 is dedicated to the Ta-barrier and Cu-seed deposition. This operation is defined as a Productive operation that is right and not right. The main part of the deposited Ta-Barrier and Cu-seed is removed anyway. Therefore, it would be more correct to define this operation as Providing. The best way is to split this operation into two: Barrier deposition and Seed deposition. Such an approach will help us to think differently and enhance or eliminate these operations separately.
Defect detection and measurements are typically performed after the Ta-barrier and Cu-seed layer deposition. There are several reasons for the defect metrology after this operation. First, the wafer is in a safe condition - the wafer is covered with a thin layer of Cu that prevents the wafer materials from oxidation by outside air. Second, the conductive thin layer ensures the defects' visibility and prevents the wafer surface's charging. The defects metrology is added to the process to ensure that the operations are completed as per requirements, the equipment operates correctly, and wafers can be released to the next operation.
The fragment of the typical pattern is shown below.
The structure that is submitted to defect metrology operation:
The main purpose of the defect metrology operation is information, and the product is information.
Effective
Ineffective
Basic functions
Components
Supersystems
Metrology tool | 10 10 |
Cu-seed layer | 5.7 |
Die | 4.3 |
Wafer | 2.9 |
The operation does not increase the product's value and only gives data to decide on the necessity of rework. The best way is to analyze the statistics and insert a reasonable skip of the operation. The criteria should be the ratio: "Gain/Cost" .
Step 12 - Cu electroplating is the operation that aims to fill in the bulk copper (Cu). The wafer is processed using electroplating equipment. The wafer is connected to the cathode (-) and placed in the electrolyte containing dissolved Cu- sulfate, CuSO4 and sulfuric acid. The anode is made of pure copper, Cu. During the process, the wafer rotates to enhance the diffusion process while the delivery of Cu-ions to the surface of the wafer. The process is performed as regular electroplating: Cu is dissolved on the anode (+) by losing electrons and forming Cu(2+) ions. Cu(2+) ions are reduced on the cathode by accepting electrons to Cu atoms that are deposited in the form of a Cu-metal layer on the surface of the wafer.
The main challenge is the formation of voids within the deposited Cu layer. The reasons for the void formation are as follows:
The deposition is always above the required level to ensure that the bubbles and some defects are mainly concentrated in the top part of the deposit and will be removed at the next operation.
The incoming structure is shown below:
The outcoming structure is shown here:
The purpose of the operation is to plate the Cu, so the product is Electroplated Cu
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Ineffective
Basic functions
Components
Supersystems
Electricity | 10 3.1 |
Electrolyte | 5 10 |
Cu(2+) ions | 4.4 |
Cu Anode | 3.1 |
Air | 2.5 0.8 |
Chuck | 2.5 |
Cu-seed layer | 2.5 |
Electric connection
to anode | 2.5 0.3 |
DC Power supply | 2.5 |
Wafer | 1.9 3.7 |
Electric connection
to wafer (cathode) | 1.3 0.3 |
H(+) iones | 0.5 |
Air bubbles | 1.5 |
H2 bubbles | 1.5 |
Electrolyte drops | 1.5 |
The electrolyte seems to be the most functional and problematic component of the system. The main problem is eliminating the remaining air bubbles. The first step to improving this operation is reducing surface tension to ensure the electrolyte penetrates all the structures.
Step 13 - Excessive Cu and Ta-barrier removal by polish aims to remove all metal parts that make contact between different metal lines that should not be connected. The operation is performed using the chemical-mechanical polishing (CMP) method.
The wafer is kept in the holder and pushed face down to the pad. A slurry containing fumed silica or other relevant material is poured on the pad to ensure the material is removed by polishing. A special conditioner cleans the pad from the residual material created during the polishing. The very general scheme of the polisher is shown below (taken from the Wikipedia):
The incoming structure is shown below:
The outcoming structure is shown here:
The purpose of the operation is to remove the excessive material - Cu, Ta, ILD. The operation's product is excessive material.
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Ineffective
Basic functions
Components
Supersystems
Pad | 10 10 |
Slurry | 8 8 |
Excessive material
on the wafer | 6 6 |
Excessive material
on the pad | 4 |
Wafer holder | 2 |
Wafer | 2 |
DI Water | 2 2 |
Conditioner | 2 |
Step 13 - Excessive Cu and Ta Barrier layer removal by polish is a corrective operation - no value is added. The operation exists because of the problematic previous operation. The excessive Cu is deposited to ensure that all defects and voids generated during the electroplating are collected in the excessive part of the deposit and can be removed at the polish.
Since the Polish is a corrective operation, it does not make any sense to improve or develop such an operation. The correct direction is to work on eliminating or simplifying the operation. For instance, it would be reasonable to remove the bulk of the Cu at the electroplater just after the completion of the electrodeposition. It is very easy process just to replace the polarity to make the wafer an anode and give (-) to the anode. It will dissolve the main affected part of the Cu and simplify the following operation - polish.
If | Nozzle remains unchanged |
---|---|
Then | Nozzle Directs Cleaning solution |
But | The dissolve residue remains on the wafer |
If | Pump remains unchanged |
---|---|
Then | Pump removes gases and creates a vacuum |
But | Pump unable to remove properly SiF4 and other gaseous by-products due to high vacuum |
If | Electrolyte remains unchanged |
---|---|
Then | Electrolyte Keeps Cu(2+) ions |
But | Electrolyte Creates Air bubbles |
The next step is to analyze the manufacturing process of the IC interconnection layer.
Generally, we need to process the structure:
To the structure:
Let's analyze all the steps needed to make an additional interconnection layer. We will use very general operations of the typical process used in many fabs for manufacturing BEOL layers.
Let's start, go to the "Model"
We need to complete 13 sequential operations to create a metal layer.
Generally speaking, two types of operations in semiconductor manufacturing aim to either deposit something or remove something.
A typical reasonable process flow is shown below:
After the photolithography operation, the pattern resist is tested with metrological operation (that is not shown in the flow). During the pattern measurements, the critical parameters are measured - Critical Dimensions Measurements (CDM) - size, location, thickness etc. The measurements are invasive therefore, the measurements are performed on the special metrocell and not on the die.
Defect metrology operation is placed after Step 11 - Barrier + Cu-seed deposition - not shown in the flow but will be analyzed in the process flow analysis.
Let's analyze the process using Process Functional Modeling, a creative thinking tool. No metrology operations were taken into account. Go to "Model"
Step 1 Etch Stop Deposition
Step 2 ILD Deposition
Step 3 Sacrificial Layer Deposition for Via
Step 4 Photolithography patterning for Via
Step 4 M - Critical Dimensions Measurements (CDM) - Via
Step 5 Via Etch
Step 6 Wet Cleaning after Via Etch
Step 7 Sacrificial Layer Deposition for Trench
Step 8 Photolithography Patterning for Trench
Step 8 M - Critical Dimensions Measurements (CDM) - Trench
Step 9 Trench Etch for Metal Line
Step 10 Wet Cleaning after Trench Etch
Step 11 Ta-Barrier + Cu-Seed layers Deposition
Step 11 M - Defects Detection & Measurements
Step 12 Cu Electroplating
Step 13 Excessive Cu and Barrier Removal by Polish
Effective
Ineffective
Productive
Providing
Corrective
Metrology
Operation Type | Does it increase cost? | Does it increase product value? | Recommendation |
---|---|---|---|
Productive | Yes | Yes | Improve |
Providing | Yes | No | Eliminate |
Corrective | Yes | No | Eliminate |
Metrology | Yes | No | Eliminate |
Operation | Type | Merit | Recommendation |
---|---|---|---|
Step 1 Etch Stop Deposition | Productive | OE 1.51 | Consider improving |
Step 2 ILD Deposition | Productive | OE 2.57 | Consider improving |
Step 3 Sacrificial Layer Deposition for Via | Providing | OE 1.35 | Consider eliminating |
Step 4 Photolithography patterning for Via | Providing | OE 4.01 | Consider eliminating |
Step 4 M - Critical Dimensions Measurements (CDM) - Via | Metrology | OE 1.9 | Consider the necessity of the information and eliminate it when possible |
Step 5 Via Etch | Productive | OE 2.88 | Consider improving |
Step 6 Wet Cleaning after Via Etch | Corrective | OE 2.4 | Do nothing and eliminate it when possible |
Step 7 Sacrificial Layer Deposition for Trench | Providing | OE 1.35 | Consider eliminating |
Step 8 Photolithography Patterning for Trench | Providing | OE 4.01 | Consider eliminating |
Step 8 M - Critical Dimensions Measurements (CDM) - Trench | Metrology | OE 1.9 | Consider the necessity of the information and eliminate it when possible |
Step 9 Trench Etch for Metal Line | Productive | OE 2.88 | Consider improving |
Step 10 Wet Cleaning after Trench Etch | Corrective | OE 2.4 | Do nothing and eliminate it when possible |
Step 11 Ta-Barrier + Cu-Seed layers Deposition | Providing | OE 2.47 | Consider eliminating |
Step 11 M - Defects Detection & Measurements | Metrology | OE 2.29 | Consider the necessity of the information and eliminate it when possible |
Step 12 Cu Electroplating | Productive | OE 1.65 | Consider improving |
Step 13 Excessive Cu and Barrier Removal by Polish | Corrective | OE 1.38 | Do nothing and eliminate it when possible |
Summary of the process functional modeling:
Some directions for the process development:
1 Step is the transformation from the structure:
To the structure:
The Etch Stop layer is mainly needed to preserve the Cu diffusion to the ILD of the top layer - the top barrier. It is typically made of Si3N4 or SiC because increased density is needed to ensure barrier properties against Cu diffusion.
The Etch Stop layer deposition is usually performed by the CVD method.
The operation aims to create the Etch Stop layer therefore, the product is the "Etch Stop Layer"
Effective
Ineffective
Basic functions
Components
Supersystems
Plasma | 10 |
CVD system | 5.5 |
Initial layer | 4 |
Gaseous Chemicals | 3.5 |
Wafer | 3 |
Cu - Initial layer | 2.5 |
ILD - Initial layer | 2.5 |
Chuck | 2 |
Vacuum pump | 10 |
By-product gases | 2.6 |
Air | 9.2 |
It is exciting results:
Plasma is the most functional component - we have to think about plasma for effective improvement of the process
The vacuum pump came out as the most problematic component of the system - we have to think about how to eliminate or replace the vacuum pump - Interesting.
Overall:
Etch stop Deposition is not a valuable operation. The operation's main purpose is to create a barrier between the Cu metal line and the top of ILD. Actually, we cover the surface of the wafer with Etch stop material, while we need it only on the top of Cu metal line.
Maybe we need to think about the material that is adsorbed bu Cu only and is not adsorbed by SiO2 - ILD. The process could be done as follows: spinon liquid, removing the liquid from the wafer at high-speed rotation (the liquid should remain only on the metallic parts), and thermal treatment of the liquid to create a top barrier layer.
So we need to develop a liquid that is adsorbed selectively by Cu and is converted to solid material after a thermal treatment.
Possible example:
A suitable liquid material that selectively adsorbs on Cu and converts to a solid after thermal treatment is Poly(methyl methacrylate) (PMMA) in a suitable solvent. Here’s how it works:
This approach allows for effective selective adsorption and subsequent solidification, making it suitable for applications in wafer fabrication.
2 Step is the deposition of the ILD layer - a transformation from structure:
To structure:
ILD is typically built of SiO2 or modified SiO2 for the reduction of dielectric permittivity. The Electric permittivity reduction is typically achieved by the creation pores and dipping with C (in the form of methyl), Fluorine
ILD deposition is typically made by the CVD process, where gaseous components are converted into a thin solid film due to the process in plasma.
The operation aims to deposit ILD; therefore, the product (target) of the step is ILD.
Effective
Ineffective
Basic functions
Components
Supersystems
Plasma | 10 |
Gaseous chemicals | 4 |
Etch Stop layer | 4 |
CVD Tool | 4 |
Previous layers | 2.7 |
Air residue | 2.7 10 |
Vacuum pump | 2 2 |
Wafer | 2 |
Chuck | 1.3 |
Gaseous by-products | 0.7 |
Stupid question. Why do we need a vacuum for ILD deposition? I see only one possible reason - to create a free pathway that is long enough for plasma creation. OK. We need to think about how to ensure plasma and avoid deep vacuum. ILD that is SiO2 or modifications of SiO2 do not need a vacuum. More than that, the lack of oxygen
3 Step is the deposition of the Sacrificial light-absorbing Layer (SLAL). The main purpose of this layer is to absorb the light during Photolithography and prevent the formation of a standing wave due to the interference of initial reflected light.
The structure:
Should be converted to the structure:
The layer is typically deposited by a spin-on procedure similar to the deposition of a photoresist.
The operation aims to deposit SLAL; therefore, the product (target) of the operation is SLAL.
Effective
Ineffective
Basic functions
Components
Supersystems
Chamber for Spin on | 10 |
ILD layer | 5 |
Furnace | 5 |
Liquid material for
Spin on deposition | 5 |
Chuck | 4 |
Air Fan | 4 |
Air | 3 |
Nozzle for
liquid material | 3 |
Wafer | 3 |
Exhaust | 2 |
Air Filter | 7.5 |
Vapor of the
liquid material | 10 |
Vapors of solid
sacrificial material | 10 |
Particles | 5 |
There are too many components. It would be easier and more effective to use hot air to solidify the Sacrificial Light Absorbing Material when it is on the wafer. So, the process seems to be like this: Wafer is kept in the chuck and rotated. The liquid stuff is poured on the rated wafer, and hot air solidifies the material on the wafer. The local flow of the air will preserve the wafer from the contamination of the layer. A chamber filter and Fan will not be needed.
4th Step is the wafer patterning using Photolithography (PL). PL is a preparation for the next step, which is Dry Etch (Plasma Etch). The purpose of the operation is to deposit the Photo Resist (PR) and create a pattern: the areas that are covered with the PR will not be affected by the Plasma etch, and opened areas will be etched by plasma.
Incoming structure:
Outcoming structure after the PL process should be as follows:
This step creates the pattern for Via etch only. The PL process generally consists of three sequential parts: deposition of the Photo Resist (PR), Exposure - optical exposing of the PR through the special mask, and Development - chemical removal of the exposed part of the PR; unexposed parts will remain on the wafer. (In the case of "negative resist, "the effect is the opposite - exposed parts will remain, while unexposed parts will be removed at the development).
The operation aims to create a patterned photoresist; therefore, its product (target) is Via Patterned PR.
Effective
Ineffective
Basic functions
Components
Supersystems
Exposed PR | 10 10 |
Liquid Developer | 10 |
Scanner | 7.5 |
Wafer | 5.8 |
Oven | 5.8 |
Liquid PR | 5.8 5.8 |
Sacrificial Light
Absorbing Layer | 5 5 |
Solid PR | 4.2 |
Development Chamber | 4.2 |
Dev Nozzle | 4.2 |
Exposure Chamber | 4.2 |
Chuck for
Spin on | 3.3 |
Liquid PR layer | 3.3 |
PR Spin on
Chamber | 2.5 |
Nozzle for
liquid PR | 2.5 |
Dev Chuck | 1.7 |
Exposure Chuck | 1.7 |
ILD layer | 1.7 |
Photolithography does not add value to the product. The PL operation is very complex, so there is no reason to develop the operation and equipment. The PL operation is very expensive and must be simplified and eliminated.
The Exposed Resist is the most functional component. So, let's document some ideas for simplification of the PL process:
Critical Dimensions Measurements (CDM) are performed after Photolithography. The main parameters of the photoresist pattern are measured and collected to decide whether to continue the wafer's process or return to the rework. The measurements are invasive, so they cannot be done on the die; they are performed on the scribe line between the dies on the specially created metro cell. Every single measurement is performed on the new metro cell because the measurements destroy the metro cell. The fragment of the typical pattern is shown below.
The main purpose of the CDM operation is the information, Product is Information.
Effective
Ineffective
Basic functions
Components
Supersystems
Metrology tool | 10 10 |
Patterned Photoresist | 4 |
Metro Cell | 3 |
Wafer | 2 |
The operation does not increase the product's value and only gives data to decide on the necessity of rework. The best way is to analyze the statistics and insert a reasonable skip of the operation. The criteria should be the ratio: "Gain/Cost" .
5th Step is to etch a Via according to the pattern that was made at the previous step - Via Photo Lithography. The etch is performed with plasma on the all surface of the wafer. The open parts will be etched, while the parts that are covered with the Photoresist (PR) will remain unchanged. The wafer is placed on the chuck, kept with static electricity and treated with plasma containing the ions and/or radicals to be able to convert the ILD in to the gas. Typically, the plasma contains fluorine that converts silicon oxide to gaseous silicon tetrafluoride.
Incoming structure:
Outcoming structure:
This step is a productive operation that provides irreversible changes and increases the value of the product.
The operation aims to create a Via within the ILD according to the patterned resist on the wafer. A via is created due to the conversion of SiO2 of ILD into gaseous SiF4, therefore, its product (target) is a SiF4 - gas.
Effective
Ineffective
Basic functions
Components
Supersystems
Fluorine ions | 10 |
Etch stop Layer | 8.9 |
Plasma | 6.7 3.9 |
ILD | 6.7 |
Pump | 5.6 10 |
Photoresist | 5.6 |
Electromagnetic field | 5.6 |
Sacrificial light
absorbing layer | 2.2 1.7 |
Residual gases | 2.2 |
The vacuum pump seems to be the most problematic component of the system. The pump is used to create a vacuum in the chamber to ensure a long enough free path for the ions and radicles. At the same time, the pump should remove the etch product - SiF4 gas. The problem is the SiF4 gas may not be removed effectively because of the high vacuum. Excessing SiF4 reduces the etch rate and can result in the under etch. SiF4 and other gaseous by-products should be pumped out properly and fast to ensure a high and stable etch rate of the process.
One of the possible solutions that came out of the 40 Inventive Principles analysis is to make the Dry etch process in pulses to allow better pumping out of the SiF4 and all other gaseous by-products.
Wet cleaning is typically performed after the Dry etch process to remove the residual photoresist and sacrificial light-absorbing material and to clean the via from the by-products formed during the Dry etch process—the interaction of plasma with pattern and ILD.
The incoming structure is shown below:
The outcoming structure should look as follows:
The purpose of the operation is to remove the temporary pattern. So, the product (target) of the operation Residue.
Effective
Ineffective
Basic functions
Components
Supersystems
Cleaning solution | 10 10 |
Chuck | 7.5 |
Wet Cleaning system | 5 |
Dissolved Residue | 5 2.5 |
Nozzle | 2.5 |
It is interesting that "Chuck" becomes a component with relatively high functionality. It occurs because it is important to dissolve the residue, but we also need to remove the dissolved residue; otherwise, the residue will remain on the wafer. The removal of the dissolved residue becomes very important.
From 40 inventive principles, we generated an idea to invert the process. Instead of pouring the chemistry on the rotating wafer, we can dip the rotating wafer face down into the solution in the bath.
Another direction for development and real innovation is to remove the residue at the previous operation - dry etch. In this case, the Wet etch operation will not be necessary and can be eliminated.
The seventh step is depositing the Sacrificial light-absorbing Layer (SLAL). This layer has two purposes: to fill in the via and avoid unnecessary etching within it, to absorb light during photolithography, and to prevent the formation of a standing wave due to the interference of initial reflected light.
The initial structure:
Should be converted to the structure:
The layer is typically deposited by a spin-on procedure similar to the deposition of a photoresist.
The operation aims to deposit SLAL; therefore, the product (target) of the operation is SLAL.
Effective
Ineffective
Basic functions
Components
Supersystems
Chamber for Spin on | 10 |
ILD layer | 5 |
Furnace | 5 |
Liquid material for
Spin on deposition | 5 |
Chuck | 4 |
Air Fan | 4 |
Air | 3 |
Nozzle for
liquid material | 3 |
Wafer | 3 |
Exhaust | 2 |
Air Filter | 7.5 |
Vapor of the
liquid material | 10 |
Vapors of solid
sacrificial material | 10 |
Particles | 5 |
Same as the Step 3 - Sacrificial Layer Deposition for Via
There are too many components. It would be easier and more effective to use hot air to solidify the Sacrificial LigLight-Absorbing Material the wafer. So, the process seems to be like this: WafThe wafer is kept in the chuck and rotated. The liquid is poured onto a rated wafer, and hot air solidifies the material on the wafer. The local flow of the air will preserve the wafer from contamination by layer. A chamber filter and Fan will not be needed.
The eighth 8 step is wafer patterning using Photolithography (PL). PL prepares the wafer for the next step, Dry Etch (Plasma Etch). The operation deposits the Photo Resist (PR) and creates a pattern: areas covered with PR are not affected by the Plasma etch, and opened areas are etched by plasma. This operation is for Trench patterning.
Incoming structure:
Outcoming structure after the PL process should be as follows:
This step creates the pattern for Trench etch only. The PL process generally consists of three sequential parts: deposition of the Photo Resist (PR), Exposure - optical exposing of the PR through the special mask, and Development - chemical removal of the exposed part of the PR; unexposed parts will remain on the wafer. (In the case of "negative resist, "the effect is the opposite - exposed parts will remain, while unexposed parts will be removed at the development).
The operation aims to create a patterned photoresist, so its product (target) is Trench-Patterned PR.
Effective
Ineffective
Basic functions
Components
Supersystems
Exposed PR | 10 10 |
Liquid Developer | 10 |
Scanner | 7.5 |
Wafer | 5.8 |
Oven | 5.8 |
Liquid PR | 5.8 5.8 |
Sacrificial Light
Absorbing Layer | 5 5 |
Solid PR | 4.2 |
Development Chamber | 4.2 |
Dev Nozzle | 4.2 |
Exposure Chamber | 4.2 |
Chuck for
Spin on | 3.3 |
Liquid PR layer | 3.3 |
PR Spin on
Chamber | 2.5 |
Nozzle for
liquid PR | 2.5 |
Dev Chuck | 1.7 |
Exposure Chuck | 1.7 |
ILD layer | 1.7 |
Photolithography does not add value to the product. The PL operation is very complex, so there is no reason to develop the operation and equipment. The PL operation is very expensive and must be simplified and eliminated.
The Exposed Resist is the most functional component. So, let's document some ideas for simplification of the PL process:
Critical Dimensions Measurements (CDM) are performed after Photolithography. The main parameters of the photoresist pattern are measured and collected to decide whether to continue the wafer's process or return to the rework. Because the measurements are invasive, they cannot be performed on the die; they are performed on the scribe line between the dies on the specially created metro cell. Every single measurement is performed on the new metro cell because they destroy the metro cell. The fragment of the typical pattern is shown below.
The structure that is submitted to CDM:
The main purpose of the CDM operation is the information, Product is Information.
Effective
Ineffective
Basic functions
Components
Supersystems
Metrology tool | 10 10 |
Patterned Photoresist | 4 |
Metro Cell | 3 |
Wafer | 2 |
The operation does not increase the product's value and only gives data to decide on the necessity of rework. The best way is to analyze the statistics and insert a reasonable skip of the operation. The criteria should be the ratio: "Gain/Cost" .
9th Step is to etch a Trench for metal wires according to the pattern made at the previous step - Trench Photo Lithography. The etch is performed with plasma on the complete surface of the wafer. The open parts will be etched, while the parts covered with the Photoresist (PR) will remain unchanged. The wafer is placed on the chuck, kept with static electricity and treated with plasma containing the ions and/or radicals to be able to convert the ILD in to the gas. Typically, the plasma contains fluorine that converts silicon oxide to gaseous silicon tetrafluoride.
Incoming structure:
Outcoming structure:
This step is a productive operation that provides irreversible changes and increases the value of the product.
The operation aims to create a Via within the ILD according to the patterned resist on the wafer. A via is created due to the conversion of SiO2 of ILD into gaseous SiF4; therefore, its product (target) is a SiF4 - gas.
Effective
Ineffective
Basic functions
Components
Supersystems
Fluorine ions | 10 |
Etch stop Layer | 8.9 |
Plasma | 6.7 3.9 |
ILD | 6.7 |
Pump | 5.6 10 |
Photoresist | 5.6 |
Electromagnetic field | 5.6 |
Sacrificial light
absorbing layer | 2.2 1.7 |
Residual gases | 2.2 |
The vacuum pump seems to be the most problematic component of the system. The pump is used to create a vacuum in the chamber to ensure a long enough free path for the ions and radicles. At the same time, the pump should remove the etch product - SiF4 gas. The problem is the SiF4 gas may not be removed effectively because of the high vacuum. Excessing SiF4 reduces the etch rate and can result in the under etch. SiF4 and other gaseous by-products should be pumped out properly and fast to ensure a high and stable etch rate of the process.
One of the possible solutions that came out of the 40 Inventive Principles analysis is to make the Dry etch process in pulses to allow better pumping out of the SiF4 and all other gaseous by-products.
Wet cleaning is typically performed after the Dry etch process to remove the residual photoresist and sacrificial light-absorbing material and to clean the via from the by-products formed during the Dry etch process—the interaction of plasma with pattern and ILD.
The incoming structure is shown below:
The outcoming structure should look as follows:
The purpose of the operation is to remove the temporary pattern. So, the product (target) of the operation Residue.
Effective
Ineffective
Basic functions
Components
Supersystems
Cleaning solution | 10 10 |
Chuck | 7.5 |
Wet Cleaning system | 5 |
Dissolved Residue | 5 2.5 |
Nozzle | 2.5 |
It is interesting that "Chuck" becomes a component with relatively high functionality. It occurs because it is important to dissolve the residue, but we also need to remove the dissolved residue; otherwise, the residue will remain on the wafer. The removal of the dissolved residue becomes very important.
From 40 inventive principles, we generated an idea to invert the process. Instead of pouring the chemistry on the rotating wafer, we can dip the rotating wafer face down into the solution in the bath.
Another direction for development and real innovation is to remove the residue at the previous operation - dry etch. In this case, the Wet etch operation will not be necessary and can be eliminated.
Step 11 is dedicated to depositing a thin layer of Tantalum (Ta) metal. Ta layer aims to prevent diffusion of copper (Cu) in the ILD, which is a silico-oxide-based dielectric material. Ta layer is a barrier between ILD and Cu. The operation's next step is disposing of a thin layer of Cu. This thin Cu layer aims to enable an electrical contact at the next operation - that is, electroplating - bulk Cu deposition by electrolysis. This thin Cu layer is named the Cu-seed layer because it allows the connection of the wafer to the Cathode and the electroplating process. Both Ta-barrier and Cu-seed layers are deposited using the PVD process - Physical Vapour Deposition. The plasma ions and radicles attract the target, which is made of relevant material - either Ta or Cu. The liberated metal aglomerates are deposited on the wafer surface, including the structure walls - vias and trenches of the metal lines.
The incoming structure is shown below:
The outcoming structure is shown below - Ta-barrier and Cu-seed layers are shown as a single black line:
The purpose of the operation is to deposit a Ta-barrier and Cu-seed layer. The Cu-seed layer is deposited on the top of the Ta-barrier layer; therefore, we can assign the Cu-seed layer as a product (target) of the operation.
Effective
Ineffective
Basic functions
Components
Supersystems
Ions & radicles | 10 4.4 |
Electromagnetic field | 7.5 |
Ta - barrier layer | 5 |
Cu agglomerates | 3.1 |
Wafer | 3.1 |
Ta agglomerates | 1.9 |
Process gas | 1.9 |
Cu - target | 1.9 |
Ta - target | 1.3 |
Chuck | 1.3 |
Vacuum pump | 1.3 1.1 |
Air | 10 |
Step 11 is dedicated to the Ta-barrier and Cu-seed deposition. This operation is defined as a Productive operation that is right and not right. The main part of the deposited Ta-Barrier and Cu-seed is removed anyway. Therefore, it would be more correct to define this operation as Providing. The best way is to split this operation into two: Barrier deposition and Seed deposition. Such an approach will help us to think differently and enhance or eliminate these operations separately.
Defect detection and measurements are typically performed after the Ta-barrier and Cu-seed layer deposition. There are several reasons for the defect metrology after this operation. First, the wafer is in a safe condition - the wafer is covered with a thin layer of Cu that prevents the wafer materials from oxidation by outside air. Second, the conductive thin layer ensures the defects' visibility and prevents the wafer surface's charging. The defects metrology is added to the process to ensure that the operations are completed as per requirements, the equipment operates correctly, and wafers can be released to the next operation.
The fragment of the typical pattern is shown below.
The structure that is submitted to defect metrology operation:
The main purpose of the defect metrology operation is information, and the product is information.
Effective
Ineffective
Basic functions
Components
Supersystems
Metrology tool | 10 10 |
Cu-seed layer | 5.7 |
Die | 4.3 |
Wafer | 2.9 |
The operation does not increase the product's value and only gives data to decide on the necessity of rework. The best way is to analyze the statistics and insert a reasonable skip of the operation. The criteria should be the ratio: "Gain/Cost" .
Step 12 - Cu electroplating is the operation that aims to fill in the bulk copper (Cu). The wafer is processed using electroplating equipment. The wafer is connected to the cathode (-) and placed in the electrolyte containing dissolved Cu- sulfate, CuSO4 and sulfuric acid. The anode is made of pure copper, Cu. During the process, the wafer rotates to enhance the diffusion process while the delivery of Cu-ions to the surface of the wafer. The process is performed as regular electroplating: Cu is dissolved on the anode (+) by losing electrons and forming Cu(2+) ions. Cu(2+) ions are reduced on the cathode by accepting electrons to Cu atoms that are deposited in the form of a Cu-metal layer on the surface of the wafer.
The main challenge is the formation of voids within the deposited Cu layer. The reasons for the void formation are as follows:
The deposition is always above the required level to ensure that the bubbles and some defects are mainly concentrated in the top part of the deposit and will be removed at the next operation.
The incoming structure is shown below:
The outcoming structure is shown here:
The purpose of the operation is to plate the Cu, so the product is Electroplated Cu
Effective
Ineffective
Basic functions
Components
Supersystems
Electricity | 10 3.1 |
Electrolyte | 5 10 |
Cu(2+) ions | 4.4 |
Cu Anode | 3.1 |
Air | 2.5 0.8 |
Chuck | 2.5 |
Cu-seed layer | 2.5 |
Electric connection
to anode | 2.5 0.3 |
DC Power supply | 2.5 |
Wafer | 1.9 3.7 |
Electric connection
to wafer (cathode) | 1.3 0.3 |
H(+) iones | 0.5 |
Air bubbles | 1.5 |
H2 bubbles | 1.5 |
Electrolyte drops | 1.5 |
The electrolyte seems to be the most functional and problematic component of the system. The main problem is eliminating the remaining air bubbles. The first step to improving this operation is reducing surface tension to ensure the electrolyte penetrates all the structures.
Step 13 - Excessive Cu and Ta-barrier removal by polish aims to remove all metal parts that make contact between different metal lines that should not be connected. The operation is performed using the chemical-mechanical polishing (CMP) method.
The wafer is kept in the holder and pushed face down to the pad. A slurry containing fumed silica or other relevant material is poured on the pad to ensure the material is removed by polishing. A special conditioner cleans the pad from the residual material created during the polishing. The very general scheme of the polisher is shown below (taken from the Wikipedia):
The incoming structure is shown below:
The outcoming structure is shown here:
The purpose of the operation is to remove the excessive material - Cu, Ta, ILD. The operation's product is excessive material.
Effective
Ineffective
Basic functions
Components
Supersystems
Pad | 10 10 |
Slurry | 8 8 |
Excessive material
on the wafer | 6 6 |
Excessive material
on the pad | 4 |
Wafer holder | 2 |
Wafer | 2 |
DI Water | 2 2 |
Conditioner | 2 |
Step 13 - Excessive Cu and Ta Barrier layer removal by polish is a corrective operation - no value is added. The operation exists because of the problematic previous operation. The excessive Cu is deposited to ensure that all defects and voids generated during the electroplating are collected in the excessive part of the deposit and can be removed at the polish.
Since the Polish is a corrective operation, it does not make any sense to improve or develop such an operation. The correct direction is to work on eliminating or simplifying the operation. For instance, it would be reasonable to remove the bulk of the Cu at the electroplater just after the completion of the electrodeposition. It is very easy process just to replace the polarity to make the wafer an anode and give (-) to the anode. It will dissolve the main affected part of the Cu and simplify the following operation - polish.
Wet cleaning is widely used in microchip manufacturing. Single wafer equipment is working as follows. A wafer rotates, and chemistry is poured from a movable nozzle. Water rinsing is performed at the end of the process. Loading of a new batch of the chemistry resulted in excursion - a strongly increased amount of defects was observed on the wafer after the processing. The project is dedicated to the failure analysis and creation of innovative solutions.
The project was dedicated to production yield improvement in microchip manufacturing. The bumps are created on the top of a wafer and used for the final test of all dies. Only good dies are taken for the packaging. All dies that fail the test will be scrapped. The process yield depends on the amount of "good" and "bad" dies. It was revealed that in some cases, the time between the end of the process and the final test impacts the yield. The longer the dwelling, the more dies fail the final test. If the dwelling exceeds hundreds of hours, the amount of failed dies becomes dramatically high, which results in the scrapping of the whole wafer. The problem was analyzed and solved.
The process is related to microelectronics - microchip manufacturing. The purpose of the process is to create a SiO2 layer on the surface of a Si wafer. Equipment: Vertical furnace to heat the wafers in the Q2 atmosphere and perform oxidation on the wafer surface. Process: The oxidation occurs on the front side and on the back side of the wafer Requirements: Create a SiO2 thin layer with a certain thickness and low sigma - low standard deviation of the thickness between the wafers and within the wafer Failure: Wafers from the lower zone have higher thickness and significantly higher within wafer sigma (standard deviation of the thickness within the wafer)