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Updated 02/4/2025
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Optimizing IC Interconnection: A Functional Approach to Innovation (Stay updated on the project's progress)

Functional Modeling of the traditional layer #

We need to create a Functional Model of IC Interconnection to understand and learn the functional and problem ranks of all components.

We will take one metal layer created above the layer below.

The purpose of the IC interconnection is to electrically connect the metal in the layer below to the metal line above. Therefore, the system's product would be Current.

The challenges are as follows:

We need a dielectric material (ILD) to be able to keep the metal line mechanically and separated electrically

ILD - Interlayer dielectric that is typically built of SiO2 or modified SiO2

The metal lines and via are made from Cu

Cu diffuses through the ILD, resulting in shortening - the creation of electrical contacts through ILD

The barrier (typically Ta) is used for preventing Cu diffusion into ILD within the layer

Etch stop layer (typically Si3N4, SiC) aims to prevent Cu diffusion to ILD on the upper layer

Cu is affected by the electromigration effect; therefore, the bottom Barrier that separates the top of the via from the metal at the low layer helps to prevent the formation of huge voids due to Cu electromigration from layer to layer

During the Functional Modeling, we need to take into account the RC-delay that affects the signal and should be as low as possible. RC-delay = R X C where R is the total resistivity of metal layers, and Vias and C is the total capacitance of vertical and horizontal gaps of dielectrics located between metal lines. The resistivity of the metal lines and metal vias should be as low as possible; the Dielectric permittivity of dielectric layers should be as low as possible.

The interconnection part is shown below:


Let's start to create a Functional Model.

Operational Effectiveness – OE

Effective

Ineffective

OE 1.76
Operational Perfectness - OP

Basic functions

Components

Supersystems

OP 0.11
Functional rank
Problematic rank
Barrier - top layer
10
10
ILD - top layer
8
2.2
Cu metal - top layer
5
1.3
Metal - bottom layer
5
Cu via - top layer
3
1
ILD - bottom layer
2
Etch stop layer
2
Barrier - bottom layer
2
0.7
Cu - diffusion
0.8
Cu electromigration voids
5

Exciting result - the most functional component for current providing is not a metal line but a component that keeps the metal line:

  • If we assign that "Barrier Keeps Metal Line" (see the basic version) - the most functional component becomes Barrier
  • If we assign that "ILD Keeps Metal Line" (next version) - the most functional component becomes ILD

The conclusion - the carrier has higher functionality than the metal line that provides electrical current.


So, we need to think about how to eliminate barriers and delegate its functions to another component - small air gaps between Cu metal lines and ILD seem to be very perspective from the standpoint of both Cu diffusion prevention and RC-delay reduction

The possible configuration can be as shown below:


The Functional Model is in the Proposed Version


The Air Gaps model seems much better and also helps to prevent void formation due to Cu electromigration - the void already exists. It might happen that due to very strong Cu-electromigration, the shape of the via and metal line will be slightly affected, but no voids will be created within the metal line or within the metal via.

Oct 13 2024 11:05:29 am
Version: Basic version, Component: Barrier - top layer #
Contradiction:
If
Barrier - top layer remains unchanged
Then
Barrier - top layer Keeps Cu metal - top layer
But
Barrier - top layer Reduces Cu metal - top layer
Improving parameter
Description of what is improving:
No diffusion of Cu or voids formation due to electromigration effect - Metal line remains unchanged
Selected improving parameter:
Shape
Worsening parameter
Description of what is worsening:
The barrier takes the volume of the via and trench therefore, the volume of the metal via and metal line becomes smaller, reducing the conductivity of the line and affecting the current as a product
Selected worsening parameter:
Loss of substance
Matching principles:
  • 3
    Local quality
  • 5
    Merging
  • 29
    Pneumatics or hydraulics
  • 35
    Parameter changes
  • Oct 18 2024 8:49:34 am
    Process Functional Modeling - Typical Process #

    The next step is to analyze the manufacturing process of the IC interconnection layer.

    Generally, we need to process the structure:


    To the structure:



    Let's analyze all the steps needed to make an additional interconnection layer. We will use very general operations of the typical process used in many fabs for manufacturing BEOL layers.

    Let's start, go to the "Model"


    We need to complete 13 sequential operations to create a metal layer.

    Generally speaking, two types of operations in semiconductor manufacturing aim to either deposit something or remove something.


    A typical reasonable process flow is shown below:



    After the photolithography operation, the pattern resist is tested with metrological operation (that is not shown in the flow). During the pattern measurements, the critical parameters are measured - Critical Dimensions Measurements (CDM) - size, location, thickness etc. The measurements are invasive therefore, the measurements are performed on the special metrocell and not on the die.

    Defect metrology operation is placed after Step 11 - Barrier + Cu-seed deposition - not shown in the flow but will be analyzed in the process flow analysis.

    Let's analyze the process using Process Functional Modeling, a creative thinking tool. No metrology operations were taken into account. Go to "Model"

    Step 1 Etch Stop Deposition

    3
    1.98
    OE 1.51

    Step 2 ILD Deposition

    3.27
    1.27
    OE 2.57

    Step 3 Sacrificial Layer Deposition for Via

    3.14
    2.32
    OE 1.35

    Step 4 Photolithography patterning for Via

    4.63
    1.16
    OE 4.01

    Step 4 M - Critical Dimensions Measurements (CDM) - Via

    4.75
    2.5
    OE 1.9

    Step 5 Via Etch

    5.7
    1.98
    OE 2.88

    Step 6 Wet Cleaning after Via Etch

    6
    2.5
    OE 2.4

    Step 7 Sacrificial Layer Deposition for Trench

    3.14
    2.32
    OE 1.35

    Step 8 Photolithography Patterning for Trench

    4.63
    1.16
    OE 4.01

    Step 8 M - Critical Dimensions Measurements (CDM) - Trench

    4.75
    2.5
    OE 1.9

    Step 9 Trench Etch for Metal Line

    5.7
    1.98
    OE 2.88

    Step 10 Wet Cleaning after Trench Etch

    6
    2.5
    OE 2.4

    Step 11 Ta-Barrier + Cu-Seed layers Deposition

    3.19
    1.29
    OE 2.47

    Step 11 M - Defects Detection & Measurements

    5.73
    2.5
    OE 2.29

    Step 12 Cu Electroplating

    2.55
    1.55
    OE 1.65

    Step 13 Excessive Cu and Barrier Removal by Polish

    4.5
    3.25
    OE 1.38
    Productive operations effectiveness

    Effective

    Ineffective

    Operation types breakdown

    Productive

    Providing

    Corrective

    Metrology

    Operation TypeDoes it increase cost?Does it increase product value?Recommendation
    Productive
    YesYesImprove
    Providing
    YesNoEliminate
    Corrective
    YesNoEliminate
    Metrology
    YesNoEliminate
    OperationTypeMeritRecommendation
    Step 1 Etch Stop Deposition
    Productive
    OE 1.51
    Consider improving
    Step 2 ILD Deposition
    Productive
    OE 2.57
    Consider improving
    Step 3 Sacrificial Layer Deposition for Via
    Providing
    OE 1.35
    Consider eliminating
    Step 4 Photolithography patterning for Via
    Providing
    OE 4.01
    Consider eliminating
    Step 4 M - Critical Dimensions Measurements (CDM) - Via
    Metrology
    OE 1.9
    Consider the necessity of the information and eliminate it when possible
    Step 5 Via Etch
    Productive
    OE 2.88
    Consider improving
    Step 6 Wet Cleaning after Via Etch
    Corrective
    OE 2.4
    Do nothing and eliminate it when possible
    Step 7 Sacrificial Layer Deposition for Trench
    Providing
    OE 1.35
    Consider eliminating
    Step 8 Photolithography Patterning for Trench
    Providing
    OE 4.01
    Consider eliminating
    Step 8 M - Critical Dimensions Measurements (CDM) - Trench
    Metrology
    OE 1.9
    Consider the necessity of the information and eliminate it when possible
    Step 9 Trench Etch for Metal Line
    Productive
    OE 2.88
    Consider improving
    Step 10 Wet Cleaning after Trench Etch
    Corrective
    OE 2.4
    Do nothing and eliminate it when possible
    Step 11 Ta-Barrier + Cu-Seed layers Deposition
    Providing
    OE 2.47
    Consider eliminating
    Step 11 M - Defects Detection & Measurements
    Metrology
    OE 2.29
    Consider the necessity of the information and eliminate it when possible
    Step 12 Cu Electroplating
    Productive
    OE 1.65
    Consider improving
    Step 13 Excessive Cu and Barrier Removal by Polish
    Corrective
    OE 1.38
    Do nothing and eliminate it when possible

    Summary of the process functional modeling:

    1. At least 16 operations, including 3 metrology operations, are needed to build one interconnection layer.
    2. The process's average effectiveness is close to 70%, which is excellent. However, only about 30% of operations contribute value to the product. Therefore, the rest of the operations should be eliminated or simplified.


    Some directions for the process development:

    1. Etch Stop is needed only above Cu to prevent Cu diffusion from the bottom Cu metal line to the top ILD. Instead of depositing the Etch Stop material with CVD, it is proposed that a process of selective deposition of PMMA with dissolved SiC or SiN be developed. The liquid can be spun on the wafer and removed from the ILD (SiO2) areas.
    2. Photolithography - Perform development of the exposed resist in wet etch equipment. More than that, why do we need to develop exposed PR at all? Exposed PR is removed by an aqueous solution, meaning it can be removed by plasma. So, the idea is to apply plasma etch directly after exposure.
    3. Wet cleaning after dry etch - Why do we need to develop exposed PR at all? Exposed PR is removed by an aqueous solution, meaning it can be removed by plasma. So, the idea is to apply plasma etch directly after exposure. The aim is to eliminate expensive wet etch operations.
    4. Polish (CMP) - To simplify the polish (CMP) operation, it is proposed that the bulk of the Cu be removed at the electroplater just after the completion of the electrodeposition. It is a straightforward process to reverse the polarity to make the wafer an anode and give (-) to the anode. This will dissolve the main affected part of the Cu and simplify the following operation - polish.
    Oct 19 2024 1:03:56 pm
    Step 1 Etch Stop Deposition #
    (by Process Functional Modeling - Typical Process)

    1 Step is the transformation from the structure:


    To the structure:


    The Etch Stop layer is mainly needed to preserve the Cu diffusion to the ILD of the top layer - the top barrier. It is typically made of Si3N4 or SiC because increased density is needed to ensure barrier properties against Cu diffusion.

    The Etch Stop layer deposition is usually performed by the CVD method.

    The operation aims to create the Etch Stop layer therefore, the product is the "Etch Stop Layer"

    Operational Effectiveness – OE

    Effective

    Ineffective

    OE 1.51
    Operational Perfectness - OP

    Basic functions

    Components

    Supersystems

    OP 0.18
    Functional rank
    Problematic rank
    Plasma
    10
    CVD system
    5.5
    Initial layer
    4
    Gaseous Chemicals
    3.5
    Wafer
    3
    Cu - Initial layer
    2.5
    ILD - Initial layer
    2.5
    Chuck
    2
    Vacuum pump
    10
    By-product gases
    2.6
    Air
    9.2

    It is exciting results:

    Plasma is the most functional component - we have to think about plasma for effective improvement of the process

    The vacuum pump came out as the most problematic component of the system - we have to think about how to eliminate or replace the vacuum pump - Interesting.


    Overall:

    Etch stop Deposition is not a valuable operation. The operation's main purpose is to create a barrier between the Cu metal line and the top of ILD. Actually, we cover the surface of the wafer with Etch stop material, while we need it only on the top of Cu metal line.


    Maybe we need to think about the material that is adsorbed bu Cu only and is not adsorbed by SiO2 - ILD. The process could be done as follows: spinon liquid, removing the liquid from the wafer at high-speed rotation (the liquid should remain only on the metallic parts), and thermal treatment of the liquid to create a top barrier layer.


    So we need to develop a liquid that is adsorbed selectively by Cu and is converted to solid material after a thermal treatment.


    Possible example:

    A suitable liquid material that selectively adsorbs on Cu and converts to a solid after thermal treatment is Poly(methyl methacrylate) (PMMA) in a suitable solvent. Here’s how it works:

    Liquid Material: PMMA Solution

    1. Composition: PMMA can be dissolved in organic solvents such as toluene or acetone to create a liquid solution. The choice of solvent can influence the adsorption characteristics on Cu and SiO2.
    2. Selective Adsorption: PMMA has a higher affinity for Cu due to its ability to interact with the metal surface, while it exhibits lower adhesion to SiO2. This allows for selective adsorption on the Cu parts of the wafer.
    3. Thermal Treatment: Upon heating, the solvent evaporates, and the PMMA undergoes a polymerization process, leading to the formation of a solid PMMA film on the Cu areas. The thermal treatment can also help in cross-linking the PMMA, enhancing its mechanical properties.

    Process Steps:

    1. Spin Coating: Apply the PMMA solution onto the wafer and spin it to achieve a uniform layer. The centrifugal force will help remove excess material from the SiO2 areas.
    2. Thermal Treatment: After spin coating, subject the wafer to a thermal treatment (e.g., baking at around 100-150°C) to evaporate the solvent and convert the PMMA into a solid film.

    Advantages:

    1. Selective Adsorption: The liquid selectively adheres to Cu, allowing for precise patterning.
    2. Solid Film Formation: The conversion to a solid film provides structural integrity and can be further processed for various applications in semiconductor manufacturing.

    Considerations:

    1. Temperature Control: Ensure that the thermal treatment does not damage the underlying structures or materials on the wafer.
    2. Solvent Choice: The choice of solvent is crucial for achieving the desired selectivity and should be tested for compatibility with both Cu and SiO2 surfaces.

    This approach allows for effective selective adsorption and subsequent solidification, making it suitable for applications in wafer fabrication.


    Oct 20 2024 10:53:40 am
    Step 2 ILD Deposition #
    (by Process Functional Modeling - Typical Process)

    2 Step is the deposition of the ILD layer - a transformation from structure:

    To structure:


    ILD is typically built of SiO2 or modified SiO2 for the reduction of dielectric permittivity. The Electric permittivity reduction is typically achieved by the creation pores and dipping with C (in the form of methyl), Fluorine

    ILD deposition is typically made by the CVD process, where gaseous components are converted into a thin solid film due to the process in plasma.


    The operation aims to deposit ILD; therefore, the product (target) of the step is ILD.

    Operational Effectiveness – OE

    Effective

    Ineffective

    OE 2.57
    Operational Perfectness - OP

    Basic functions

    Components

    Supersystems

    OP 0.23
    Functional rank
    Problematic rank
    Plasma
    10
    Gaseous chemicals
    4
    Etch Stop layer
    4
    CVD Tool
    4
    Previous layers
    2.7
    Air residue
    2.7
    10
    Vacuum pump
    2
    2
    Wafer
    2
    Chuck
    1.3
    Gaseous by-products
    0.7

    Stupid question. Why do we need a vacuum for ILD deposition? I see only one possible reason - to create a free pathway that is long enough for plasma creation. OK. We need to think about how to ensure plasma and avoid deep vacuum. ILD that is SiO2 or modifications of SiO2 do not need a vacuum. More than that, the lack of oxygen

    Oct 20 2024 10:54:15 am
    Step 3 Sacrificial Layer Deposition for Via #
    (by Process Functional Modeling - Typical Process)

    3 Step is the deposition of the Sacrificial light-absorbing Layer (SLAL). The main purpose of this layer is to absorb the light during Photolithography and prevent the formation of a standing wave due to the interference of initial reflected light.

    The structure:



    Should be converted to the structure:


    The layer is typically deposited by a spin-on procedure similar to the deposition of a photoresist.


    The operation aims to deposit SLAL; therefore, the product (target) of the operation is SLAL.

    Operational Effectiveness – OE

    Effective

    Ineffective

    OE 1.35
    Operational Perfectness - OP

    Basic functions

    Components

    Supersystems

    OP 0.21
    Functional rank
    Problematic rank
    Chamber for Spin on
    10
    ILD layer
    5
    Furnace
    5
    Liquid material for Spin on deposition
    5
    Chuck
    4
    Air Fan
    4
    Air
    3
    Nozzle for liquid material
    3
    Wafer
    3
    Exhaust
    2
    Air Filter
    7.5
    Vapor of the liquid material
    10
    Vapors of solid sacrificial material
    10
    Particles
    5

    There are too many components. It would be easier and more effective to use hot air to solidify the Sacrificial Light Absorbing Material when it is on the wafer. So, the process seems to be like this: Wafer is kept in the chuck and rotated. The liquid stuff is poured on the rated wafer, and hot air solidifies the material on the wafer. The local flow of the air will preserve the wafer from the contamination of the layer. A chamber filter and Fan will not be needed.

    Oct 20 2024 10:55:01 am
    Step 4 Photolithography patterning for Via #
    (by Process Functional Modeling - Typical Process)

    4th Step is the wafer patterning using Photolithography (PL). PL is a preparation for the next step, which is Dry Etch (Plasma Etch). The purpose of the operation is to deposit the Photo Resist (PR) and create a pattern: the areas that are covered with the PR will not be affected by the Plasma etch, and opened areas will be etched by plasma.


    Incoming structure:


    Outcoming structure after the PL process should be as follows:



    This step creates the pattern for Via etch only. The PL process generally consists of three sequential parts: deposition of the Photo Resist (PR), Exposure - optical exposing of the PR through the special mask, and Development - chemical removal of the exposed part of the PR; unexposed parts will remain on the wafer. (In the case of "negative resist, "the effect is the opposite - exposed parts will remain, while unexposed parts will be removed at the development).


    The operation aims to create a patterned photoresist; therefore, its product (target) is Via Patterned PR.

    Operational Effectiveness – OE

    Effective

    Ineffective

    OE 4.01
    Operational Perfectness - OP

    Basic functions

    Components

    Supersystems

    OP 0.09
    Functional rank
    Problematic rank
    Exposed PR
    10
    10
    Liquid Developer
    10
    Scanner
    7.5
    Wafer
    5.8
    Oven
    5.8
    Liquid PR
    5.8
    5.8
    Sacrificial Light Absorbing Layer
    5
    5
    Solid PR
    4.2
    Development Chamber
    4.2
    Dev Nozzle
    4.2
    Exposure Chamber
    4.2
    Chuck for Spin on
    3.3
    Liquid PR layer
    3.3
    PR Spin on Chamber
    2.5
    Nozzle for liquid PR
    2.5
    Dev Chuck
    1.7
    Exposure Chuck
    1.7
    ILD layer
    1.7

    Photolithography does not add value to the product. The PL operation is very complex, so there is no reason to develop the operation and equipment. The PL operation is very expensive and must be simplified and eliminated.

    The Exposed Resist is the most functional component. So, let's document some ideas for simplification of the PL process:

    1. Why do we develop within the costly PL equipment? Developing the exposed resist is just a wet etch/clean process that can be performed with regular cheap wet cleaning equipment.
    2. Why do we need to develop exposed PR at all? Exposed PR is removed by an aqueous solution, this means that it can be removed by plasma. So, the idea is to apply plasma etch directly after exposure.
    Oct 20 2024 10:56:01 am
    Step 4 M - Critical Dimensions Measurements (CDM) - Via #
    (by Process Functional Modeling - Typical Process)

    Critical Dimensions Measurements (CDM) are performed after Photolithography. The main parameters of the photoresist pattern are measured and collected to decide whether to continue the wafer's process or return to the rework. The measurements are invasive, so they cannot be done on the die; they are performed on the scribe line between the dies on the specially created metro cell. Every single measurement is performed on the new metro cell because the measurements destroy the metro cell. The fragment of the typical pattern is shown below.


    The main purpose of the CDM operation is the information, Product is Information.

    Operational Effectiveness – OE

    Effective

    Ineffective

    OE 1.9
    Operational Perfectness - OP

    Basic functions

    Components

    Supersystems

    Functional rank
    Problematic rank
    Metrology tool
    10
    10
    Patterned Photoresist
    4
    Metro Cell
    3
    Wafer
    2

    The operation does not increase the product's value and only gives data to decide on the necessity of rework. The best way is to analyze the statistics and insert a reasonable skip of the operation. The criteria should be the ratio: "Gain/Cost" .

    Dec 6 2024 9:09:35 am
    Step 5 Via Etch #
    (by Process Functional Modeling - Typical Process)

    5th Step is to etch a Via according to the pattern that was made at the previous step - Via Photo Lithography. The etch is performed with plasma on the all surface of the wafer. The open parts will be etched, while the parts that are covered with the Photoresist (PR) will remain unchanged. The wafer is placed on the chuck, kept with static electricity and treated with plasma containing the ions and/or radicals to be able to convert the ILD in to the gas. Typically, the plasma contains fluorine that converts silicon oxide to gaseous silicon tetrafluoride.

    Incoming structure:


    Outcoming structure:


    This step is a productive operation that provides irreversible changes and increases the value of the product.


    The operation aims to create a Via within the ILD according to the patterned resist on the wafer. A via is created due to the conversion of SiO2 of ILD into gaseous SiF4, therefore, its product (target) is a SiF4 - gas.

    Operational Effectiveness – OE

    Effective

    Ineffective

    OE 2.88
    Operational Perfectness - OP

    Basic functions

    Components

    Supersystems

    OP 0.44
    Functional rank
    Problematic rank
    Fluorine ions
    10
    Etch stop Layer
    8.9
    Plasma
    6.7
    3.9
    ILD
    6.7
    Pump
    5.6
    10
    Photoresist
    5.6
    Electromagnetic field
    5.6
    Sacrificial light absorbing layer
    2.2
    1.7
    Residual gases
    2.2

    The vacuum pump seems to be the most problematic component of the system. The pump is used to create a vacuum in the chamber to ensure a long enough free path for the ions and radicles. At the same time, the pump should remove the etch product - SiF4 gas. The problem is the SiF4 gas may not be removed effectively because of the high vacuum. Excessing SiF4 reduces the etch rate and can result in the under etch. SiF4 and other gaseous by-products should be pumped out properly and fast to ensure a high and stable etch rate of the process.

    One of the possible solutions that came out of the 40 Inventive Principles analysis is to make the Dry etch process in pulses to allow better pumping out of the SiF4 and all other gaseous by-products.

    Oct 20 2024 10:57:00 am
    Step 6 Wet Cleaning after Via Etch #
    (by Process Functional Modeling - Typical Process)

    Wet cleaning is typically performed after the Dry etch process to remove the residual photoresist and sacrificial light-absorbing material and to clean the via from the by-products formed during the Dry etch process—the interaction of plasma with pattern and ILD.

    The incoming structure is shown below:


    The outcoming structure should look as follows:


    The purpose of the operation is to remove the temporary pattern. So, the product (target) of the operation Residue.

    Operational Effectiveness – OE

    Effective

    Ineffective

    OE 2.4
    Operational Perfectness - OP

    Basic functions

    Components

    Supersystems

    OP 0.18
    Functional rank
    Problematic rank
    Cleaning solution
    10
    10
    Chuck
    7.5
    Wet Cleaning system
    5
    Dissolved Residue
    5
    2.5
    Nozzle
    2.5

    It is interesting that "Chuck" becomes a component with relatively high functionality. It occurs because it is important to dissolve the residue, but we also need to remove the dissolved residue; otherwise, the residue will remain on the wafer. The removal of the dissolved residue becomes very important.


    From 40 inventive principles, we generated an idea to invert the process. Instead of pouring the chemistry on the rotating wafer, we can dip the rotating wafer face down into the solution in the bath.


    Another direction for development and real innovation is to remove the residue at the previous operation - dry etch. In this case, the Wet etch operation will not be necessary and can be eliminated.

    Oct 20 2024 10:57:48 am
    Step 7 Sacrificial Layer Deposition for Trench #
    (by Process Functional Modeling - Typical Process)

    The seventh step is depositing the Sacrificial light-absorbing Layer (SLAL). This layer has two purposes: to fill in the via and avoid unnecessary etching within it, to absorb light during photolithography, and to prevent the formation of a standing wave due to the interference of initial reflected light.


    The initial structure:




    Should be converted to the structure:



    The layer is typically deposited by a spin-on procedure similar to the deposition of a photoresist.


    The operation aims to deposit SLAL; therefore, the product (target) of the operation is SLAL.

    Operational Effectiveness – OE

    Effective

    Ineffective

    OE 1.35
    Operational Perfectness - OP

    Basic functions

    Components

    Supersystems

    OP 0.21
    Functional rank
    Problematic rank
    Chamber for Spin on
    10
    ILD layer
    5
    Furnace
    5
    Liquid material for Spin on deposition
    5
    Chuck
    4
    Air Fan
    4
    Air
    3
    Nozzle for liquid material
    3
    Wafer
    3
    Exhaust
    2
    Air Filter
    7.5
    Vapor of the liquid material
    10
    Vapors of solid sacrificial material
    10
    Particles
    5

    Same as the Step 3 - Sacrificial Layer Deposition for Via

    There are too many components. It would be easier and more effective to use hot air to solidify the Sacrificial LigLight-Absorbing Material the wafer. So, the process seems to be like this: WafThe wafer is kept in the chuck and rotated. The liquid is poured onto a rated wafer, and hot air solidifies the material on the wafer. The local flow of the air will preserve the wafer from contamination by layer. A chamber filter and Fan will not be needed.

    Dec 11 2024 11:21:44 am
    Step 8 Photolithography Patterning for Trench #
    (by Process Functional Modeling - Typical Process)

    The eighth 8 step is wafer patterning using Photolithography (PL). PL prepares the wafer for the next step, Dry Etch (Plasma Etch). The operation deposits the Photo Resist (PR) and creates a pattern: areas covered with PR are not affected by the Plasma etch, and opened areas are etched by plasma. This operation is for Trench patterning.


    Incoming structure:


    Outcoming structure after the PL process should be as follows:



    This step creates the pattern for Trench etch only. The PL process generally consists of three sequential parts: deposition of the Photo Resist (PR), Exposure - optical exposing of the PR through the special mask, and Development - chemical removal of the exposed part of the PR; unexposed parts will remain on the wafer. (In the case of "negative resist, "the effect is the opposite - exposed parts will remain, while unexposed parts will be removed at the development).


    The operation aims to create a patterned photoresist, so its product (target) is Trench-Patterned PR.

    Operational Effectiveness – OE

    Effective

    Ineffective

    OE 4.01
    Operational Perfectness - OP

    Basic functions

    Components

    Supersystems

    OP 0.09
    Functional rank
    Problematic rank
    Exposed PR
    10
    10
    Liquid Developer
    10
    Scanner
    7.5
    Wafer
    5.8
    Oven
    5.8
    Liquid PR
    5.8
    5.8
    Sacrificial Light Absorbing Layer
    5
    5
    Solid PR
    4.2
    Development Chamber
    4.2
    Dev Nozzle
    4.2
    Exposure Chamber
    4.2
    Chuck for Spin on
    3.3
    Liquid PR layer
    3.3
    PR Spin on Chamber
    2.5
    Nozzle for liquid PR
    2.5
    Dev Chuck
    1.7
    Exposure Chuck
    1.7
    ILD layer
    1.7

    Photolithography does not add value to the product. The PL operation is very complex, so there is no reason to develop the operation and equipment. The PL operation is very expensive and must be simplified and eliminated.

    The Exposed Resist is the most functional component. So, let's document some ideas for simplification of the PL process:

    1. Why do we develop within the costly PL equipment? Developing the exposed resist is just a wet etch/clean process that can be performed with regular cheap wet cleaning equipment.
    2. Why do we need to develop exposed PR at all? Exposed PR is removed by an aqueous solution, this means that it can be removed by plasma. So, the idea is to apply plasma etch directly after exposure.
    Dec 11 2024 11:42:06 am
    Step 8 M - Critical Dimensions Measurements (CDM) - Trench #
    (by Process Functional Modeling - Typical Process)

    Critical Dimensions Measurements (CDM) are performed after Photolithography. The main parameters of the photoresist pattern are measured and collected to decide whether to continue the wafer's process or return to the rework. Because the measurements are invasive, they cannot be performed on the die; they are performed on the scribe line between the dies on the specially created metro cell. Every single measurement is performed on the new metro cell because they destroy the metro cell. The fragment of the typical pattern is shown below.


    The structure that is submitted to CDM:



    The main purpose of the CDM operation is the information, Product is Information.

    Operational Effectiveness – OE

    Effective

    Ineffective

    OE 1.9
    Operational Perfectness - OP

    Basic functions

    Components

    Supersystems

    Functional rank
    Problematic rank
    Metrology tool
    10
    10
    Patterned Photoresist
    4
    Metro Cell
    3
    Wafer
    2

    The operation does not increase the product's value and only gives data to decide on the necessity of rework. The best way is to analyze the statistics and insert a reasonable skip of the operation. The criteria should be the ratio: "Gain/Cost" .

    Dec 11 2024 12:09:20 pm
    Step 9 Trench Etch for Metal Line #
    (by Process Functional Modeling - Typical Process)

    9th Step is to etch a Trench for metal wires according to the pattern made at the previous step - Trench Photo Lithography. The etch is performed with plasma on the complete surface of the wafer. The open parts will be etched, while the parts covered with the Photoresist (PR) will remain unchanged. The wafer is placed on the chuck, kept with static electricity and treated with plasma containing the ions and/or radicals to be able to convert the ILD in to the gas. Typically, the plasma contains fluorine that converts silicon oxide to gaseous silicon tetrafluoride.

    Incoming structure:



    Outcoming structure:




    This step is a productive operation that provides irreversible changes and increases the value of the product.


    The operation aims to create a Via within the ILD according to the patterned resist on the wafer. A via is created due to the conversion of SiO2 of ILD into gaseous SiF4; therefore, its product (target) is a SiF4 - gas.

    Operational Effectiveness – OE

    Effective

    Ineffective

    OE 2.88
    Operational Perfectness - OP

    Basic functions

    Components

    Supersystems

    OP 0.44
    Functional rank
    Problematic rank
    Fluorine ions
    10
    Etch stop Layer
    8.9
    Plasma
    6.7
    3.9
    ILD
    6.7
    Pump
    5.6
    10
    Photoresist
    5.6
    Electromagnetic field
    5.6
    Sacrificial light absorbing layer
    2.2
    1.7
    Residual gases
    2.2

    The vacuum pump seems to be the most problematic component of the system. The pump is used to create a vacuum in the chamber to ensure a long enough free path for the ions and radicles. At the same time, the pump should remove the etch product - SiF4 gas. The problem is the SiF4 gas may not be removed effectively because of the high vacuum. Excessing SiF4 reduces the etch rate and can result in the under etch. SiF4 and other gaseous by-products should be pumped out properly and fast to ensure a high and stable etch rate of the process.

    One of the possible solutions that came out of the 40 Inventive Principles analysis is to make the Dry etch process in pulses to allow better pumping out of the SiF4 and all other gaseous by-products.

    Dec 12 2024 8:07:31 am
    Step 10 Wet Cleaning after Trench Etch #
    (by Process Functional Modeling - Typical Process)

    Wet cleaning is typically performed after the Dry etch process to remove the residual photoresist and sacrificial light-absorbing material and to clean the via from the by-products formed during the Dry etch process—the interaction of plasma with pattern and ILD.

    The incoming structure is shown below:



    The outcoming structure should look as follows:



    The purpose of the operation is to remove the temporary pattern. So, the product (target) of the operation Residue.

    Operational Effectiveness – OE

    Effective

    Ineffective

    OE 2.4
    Operational Perfectness - OP

    Basic functions

    Components

    Supersystems

    OP 0.18
    Functional rank
    Problematic rank
    Cleaning solution
    10
    10
    Chuck
    7.5
    Wet Cleaning system
    5
    Dissolved Residue
    5
    2.5
    Nozzle
    2.5

    It is interesting that "Chuck" becomes a component with relatively high functionality. It occurs because it is important to dissolve the residue, but we also need to remove the dissolved residue; otherwise, the residue will remain on the wafer. The removal of the dissolved residue becomes very important.


    From 40 inventive principles, we generated an idea to invert the process. Instead of pouring the chemistry on the rotating wafer, we can dip the rotating wafer face down into the solution in the bath.


    Another direction for development and real innovation is to remove the residue at the previous operation - dry etch. In this case, the Wet etch operation will not be necessary and can be eliminated.

    Dec 12 2024 3:38:28 pm
    Step 11 Ta-Barrier + Cu-Seed layers Deposition #
    (by Process Functional Modeling - Typical Process)

    Step 11 is dedicated to depositing a thin layer of Tantalum (Ta) metal. Ta layer aims to prevent diffusion of copper (Cu) in the ILD, which is a silico-oxide-based dielectric material. Ta layer is a barrier between ILD and Cu. The operation's next step is disposing of a thin layer of Cu. This thin Cu layer aims to enable an electrical contact at the next operation - that is, electroplating - bulk Cu deposition by electrolysis. This thin Cu layer is named the Cu-seed layer because it allows the connection of the wafer to the Cathode and the electroplating process. Both Ta-barrier and Cu-seed layers are deposited using the PVD process - Physical Vapour Deposition. The plasma ions and radicles attract the target, which is made of relevant material - either Ta or Cu. The liberated metal aglomerates are deposited on the wafer surface, including the structure walls - vias and trenches of the metal lines.


    The incoming structure is shown below:




    The outcoming structure is shown below - Ta-barrier and Cu-seed layers are shown as a single black line:


    The purpose of the operation is to deposit a Ta-barrier and Cu-seed layer. The Cu-seed layer is deposited on the top of the Ta-barrier layer; therefore, we can assign the Cu-seed layer as a product (target) of the operation.

    Operational Effectiveness – OE

    Effective

    Ineffective

    OE 2.47
    Operational Perfectness - OP

    Basic functions

    Components

    Supersystems

    OP 0.2
    Functional rank
    Problematic rank
    Ions & radicles
    10
    4.4
    Electromagnetic field
    7.5
    Ta - barrier layer
    5
    Cu agglomerates
    3.1
    Wafer
    3.1
    Ta agglomerates
    1.9
    Process gas
    1.9
    Cu - target
    1.9
    Ta - target
    1.3
    Chuck
    1.3
    Vacuum pump
    1.3
    1.1
    Air
    10

    Step 11 is dedicated to the Ta-barrier and Cu-seed deposition. This operation is defined as a Productive operation that is right and not right. The main part of the deposited Ta-Barrier and Cu-seed is removed anyway. Therefore, it would be more correct to define this operation as Providing. The best way is to split this operation into two: Barrier deposition and Seed deposition. Such an approach will help us to think differently and enhance or eliminate these operations separately.

    Oct 20 2024 11:04:21 am
    Step 11 M - Defects Detection & Measurements #
    (by Process Functional Modeling - Typical Process)

    Defect detection and measurements are typically performed after the Ta-barrier and Cu-seed layer deposition. There are several reasons for the defect metrology after this operation. First, the wafer is in a safe condition - the wafer is covered with a thin layer of Cu that prevents the wafer materials from oxidation by outside air. Second, the conductive thin layer ensures the defects' visibility and prevents the wafer surface's charging. The defects metrology is added to the process to ensure that the operations are completed as per requirements, the equipment operates correctly, and wafers can be released to the next operation.

    The fragment of the typical pattern is shown below.


    The structure that is submitted to defect metrology operation:




    The main purpose of the defect metrology operation is information, and the product is information.

    Operational Effectiveness – OE

    Effective

    Ineffective

    OE 2.29
    Operational Perfectness - OP

    Basic functions

    Components

    Supersystems

    Functional rank
    Problematic rank
    Metrology tool
    10
    10
    Cu-seed layer
    5.7
    Die
    4.3
    Wafer
    2.9

    The operation does not increase the product's value and only gives data to decide on the necessity of rework. The best way is to analyze the statistics and insert a reasonable skip of the operation. The criteria should be the ratio: "Gain/Cost" .

    Dec 21 2024 10:23:45 am
    Step 12 Cu Electroplating #
    (by Process Functional Modeling - Typical Process)

    Step 12 - Cu electroplating is the operation that aims to fill in the bulk copper (Cu). The wafer is processed using electroplating equipment. The wafer is connected to the cathode (-) and placed in the electrolyte containing dissolved Cu- sulfate, CuSO4 and sulfuric acid. The anode is made of pure copper, Cu. During the process, the wafer rotates to enhance the diffusion process while the delivery of Cu-ions to the surface of the wafer. The process is performed as regular electroplating: Cu is dissolved on the anode (+) by losing electrons and forming Cu(2+) ions. Cu(2+) ions are reduced on the cathode by accepting electrons to Cu atoms that are deposited in the form of a Cu-metal layer on the surface of the wafer.

    The main challenge is the formation of voids within the deposited Cu layer. The reasons for the void formation are as follows:

    1. Bubble formation: H(+) discharge and formation of H2 bubbles. This typically occurs when the voltage is too high, which results from improper electrical contact, the Cu-seed layer not being thick enough, etc.
    2. Bubbles remaining: Air should be completely replaced by the electrolyte, but if air bubbles remain encapsulated by the electrolyte and Cu deposit
    3. Electrolyte drops: the electrolyte should be completely replaced by the Cu that is electroplated during the process, but the growing Cu deposit can encapsulate some drops of the electrolyte.

    The deposition is always above the required level to ensure that the bubbles and some defects are mainly concentrated in the top part of the deposit and will be removed at the next operation.


    The incoming structure is shown below:


    The outcoming structure is shown here:


    The purpose of the operation is to plate the Cu, so the product is Electroplated Cu

    Operational Effectiveness – OE

    Effective

    Ineffective

    OE 1.65
    Operational Perfectness - OP

    Basic functions

    Components

    Supersystems

    OP 0.07
    Functional rank
    Problematic rank
    Electricity
    10
    3.1
    Electrolyte
    5
    10
    Cu(2+) ions
    4.4
    Cu Anode
    3.1
    Air
    2.5
    0.8
    Chuck
    2.5
    Cu-seed layer
    2.5
    Electric connection to anode
    2.5
    0.3
    DC Power supply
    2.5
    Wafer
    1.9
    3.7
    Electric connection to wafer (cathode)
    1.3
    0.3
    H(+) iones
    0.5
    Air bubbles
    1.5
    H2 bubbles
    1.5
    Electrolyte drops
    1.5

    The electrolyte seems to be the most functional and problematic component of the system. The main problem is eliminating the remaining air bubbles. The first step to improving this operation is reducing surface tension to ensure the electrolyte penetrates all the structures.

    Oct 20 2024 11:05:30 am
    Step 13 Excessive Cu and Barrier Removal by Polish #
    (by Process Functional Modeling - Typical Process)

    Step 13 - Excessive Cu and Ta-barrier removal by polish aims to remove all metal parts that make contact between different metal lines that should not be connected. The operation is performed using the chemical-mechanical polishing (CMP) method.

    The wafer is kept in the holder and pushed face down to the pad. A slurry containing fumed silica or other relevant material is poured on the pad to ensure the material is removed by polishing. A special conditioner cleans the pad from the residual material created during the polishing. The very general scheme of the polisher is shown below (taken from the Wikipedia):


    The incoming structure is shown below:



    The outcoming structure is shown here:



    The purpose of the operation is to remove the excessive material - Cu, Ta, ILD. The operation's product is excessive material.

    Operational Effectiveness – OE

    Effective

    Ineffective

    OE 1.38
    Operational Perfectness - OP

    Basic functions

    Components

    Supersystems

    OP 0.27
    Functional rank
    Problematic rank
    Pad
    10
    10
    Slurry
    8
    8
    Excessive material on the wafer
    6
    6
    Excessive material on the pad
    4
    Wafer holder
    2
    Wafer
    2
    DI Water
    2
    2
    Conditioner
    2

    Step 13 - Excessive Cu and Ta Barrier layer removal by polish is a corrective operation - no value is added. The operation exists because of the problematic previous operation. The excessive Cu is deposited to ensure that all defects and voids generated during the electroplating are collected in the excessive part of the deposit and can be removed at the polish.

    Since the Polish is a corrective operation, it does not make any sense to improve or develop such an operation. The correct direction is to work on eliminating or simplifying the operation. For instance, it would be reasonable to remove the bulk of the Cu at the electroplater just after the completion of the electrodeposition. It is very easy process just to replace the polarity to make the wafer an anode and give (-) to the anode. It will dissolve the main affected part of the Cu and simplify the following operation - polish.

    Oct 20 2024 11:06:26 am
    Component: Nozzle #
    Contradiction:
    If
    Nozzle remains unchanged
    Then
    Nozzle Directs Cleaning solution
    But
    The dissolve residue remains on the wafer
    Improving parameter
    Description of what is improving:
    The nozzle directs the solution to the wafer to dissolve the residue
    Selected improving parameter:
    Shape
    Worsening parameter
    Description of what is worsening:
    The cleaning solution, together with the dissolved residue remains on the wafer and should be removed by the wafer rotation
    Selected worsening parameter:
    Object generated harmful factors
    Matching principles:
  • 1
    Segmentation
  • 35
    Parameter changes
  • Dec 8 2024 11:20:46 am
    Component: Pump #
    Contradiction:
    If
    Pump remains unchanged
    Then
    Pump removes gases and creates a vacuum
    But
    Pump unable to remove properly SiF4 and other gaseous by-products due to high vacuum
    Improving parameter
    Description of what is improving:
    High vacuum
    Selected improving parameter:
    Ease of operation
    Worsening parameter
    Description of what is worsening:
    Gaseous by-products are not removed and the etch rate reduces
    Selected worsening parameter:
    Use of energy by moving object
    Matching principles:
  • 1
    Segmentation
  • 13
    The Other way around
  • 24
    Intermediary
  • Dec 25 2024 10:56:33 am
    Component: Electrolyte #
    Contradiction:
    If
    Electrolyte remains unchanged
    Then
    Electrolyte Keeps Cu(2+) ions
    But
    Electrolyte Creates Air bubbles
    Improving parameter
    Description of what is improving:
    Creation of Cu(2+) ions that are needed for the electrolysis
    Selected improving parameter:
    Ease of manufacture
    Worsening parameter
    Description of what is worsening:
    The electrolyte does not perfectly remove all the air from the wafer surface and structure
    Selected worsening parameter:
    Area of stationary object
    Matching principles:
  • 16
    Partial or excessive action
  • 40
    Composite materials
  • Dec 27 2024 12:01:16 pm
    (In development) Process Functional Modeling - New Process #

    The next step is to analyze the manufacturing process of the IC interconnection layer.

    Generally, we need to process the structure:


    To the structure:



    Let's analyze all the steps needed to make an additional interconnection layer. We will use very general operations of the typical process used in many fabs for manufacturing BEOL layers.

    Let's start, go to the "Model"


    We need to complete 13 sequential operations to create a metal layer.

    Generally speaking, two types of operations in semiconductor manufacturing aim to either deposit something or remove something.


    A typical reasonable process flow is shown below:



    After the photolithography operation, the pattern resist is tested with metrological operation (that is not shown in the flow). During the pattern measurements, the critical parameters are measured - Critical Dimensions Measurements (CDM) - size, location, thickness etc. The measurements are invasive therefore, the measurements are performed on the special metrocell and not on the die.

    Defect metrology operation is placed after Step 11 - Barrier + Cu-seed deposition - not shown in the flow but will be analyzed in the process flow analysis.

    Let's analyze the process using Process Functional Modeling, a creative thinking tool. No metrology operations were taken into account. Go to "Model"

    Step 1 Etch Stop Deposition

    3
    1.98
    OE 1.51

    Step 2 ILD Deposition

    3.27
    1.27
    OE 2.57

    Step 3 Sacrificial Layer Deposition for Via

    3.14
    2.32
    OE 1.35

    Step 4 Photolithography patterning for Via

    4.63
    1.16
    OE 4.01

    Step 4 M - Critical Dimensions Measurements (CDM) - Via

    4.75
    2.5
    OE 1.9

    Step 5 Via Etch

    5.7
    1.98
    OE 2.88

    Step 6 Wet Cleaning after Via Etch

    6
    2.5
    OE 2.4

    Step 7 Sacrificial Layer Deposition for Trench

    3.14
    2.32
    OE 1.35

    Step 8 Photolithography Patterning for Trench

    4.63
    1.16
    OE 4.01

    Step 8 M - Critical Dimensions Measurements (CDM) - Trench

    4.75
    2.5
    OE 1.9

    Step 9 Trench Etch for Metal Line

    5.7
    1.98
    OE 2.88

    Step 10 Wet Cleaning after Trench Etch

    6
    2.5
    OE 2.4

    Step 11 Ta-Barrier + Cu-Seed layers Deposition

    3.19
    1.29
    OE 2.47

    Step 11 M - Defects Detection & Measurements

    5.73
    2.5
    OE 2.29

    Step 12 Cu Electroplating

    2.55
    1.55
    OE 1.65

    Step 13 Excessive Cu and Barrier Removal by Polish

    4.5
    3.25
    OE 1.38
    Productive operations effectiveness

    Effective

    Ineffective

    Operation types breakdown

    Productive

    Providing

    Corrective

    Metrology

    Operation TypeDoes it increase cost?Does it increase product value?Recommendation
    Productive
    YesYesImprove
    Providing
    YesNoEliminate
    Corrective
    YesNoEliminate
    Metrology
    YesNoEliminate
    OperationTypeMeritRecommendation
    Step 1 Etch Stop Deposition
    Productive
    OE 1.51
    Consider improving
    Step 2 ILD Deposition
    Productive
    OE 2.57
    Consider improving
    Step 3 Sacrificial Layer Deposition for Via
    Providing
    OE 1.35
    Consider eliminating
    Step 4 Photolithography patterning for Via
    Providing
    OE 4.01
    Consider eliminating
    Step 4 M - Critical Dimensions Measurements (CDM) - Via
    Metrology
    OE 1.9
    Consider the necessity of the information and eliminate it when possible
    Step 5 Via Etch
    Productive
    OE 2.88
    Consider improving
    Step 6 Wet Cleaning after Via Etch
    Corrective
    OE 2.4
    Do nothing and eliminate it when possible
    Step 7 Sacrificial Layer Deposition for Trench
    Providing
    OE 1.35
    Consider eliminating
    Step 8 Photolithography Patterning for Trench
    Providing
    OE 4.01
    Consider eliminating
    Step 8 M - Critical Dimensions Measurements (CDM) - Trench
    Metrology
    OE 1.9
    Consider the necessity of the information and eliminate it when possible
    Step 9 Trench Etch for Metal Line
    Productive
    OE 2.88
    Consider improving
    Step 10 Wet Cleaning after Trench Etch
    Corrective
    OE 2.4
    Do nothing and eliminate it when possible
    Step 11 Ta-Barrier + Cu-Seed layers Deposition
    Providing
    OE 2.47
    Consider eliminating
    Step 11 M - Defects Detection & Measurements
    Metrology
    OE 2.29
    Consider the necessity of the information and eliminate it when possible
    Step 12 Cu Electroplating
    Productive
    OE 1.65
    Consider improving
    Step 13 Excessive Cu and Barrier Removal by Polish
    Corrective
    OE 1.38
    Do nothing and eliminate it when possible

    Summary of the process functional modeling:

    1. At least 16 operations, including 3 metrology operations, are needed to build one interconnection layer.
    2. The process's average effectiveness is close to 70%, which is excellent. However, only about 30% of operations contribute value to the product. Therefore, the rest of the operations should be eliminated or simplified.


    Some directions for the process development:

    1. Etch Stop is needed only above Cu to prevent Cu diffusion from the bottom Cu metal line to the top ILD. Instead of depositing the Etch Stop material with CVD, it is proposed that a process of selective deposition of PMMA with dissolved SiC or SiN be developed. The liquid can be spun on the wafer and removed from the ILD (SiO2) areas.
    2. Photolithography - Perform development of the exposed resist in wet etch equipment. More than that, why do we need to develop exposed PR at all? Exposed PR is removed by an aqueous solution, meaning it can be removed by plasma. So, the idea is to apply plasma etch directly after exposure.
    3. Wet cleaning after dry etch - Why do we need to develop exposed PR at all? Exposed PR is removed by an aqueous solution, meaning it can be removed by plasma. So, the idea is to apply plasma etch directly after exposure. The aim is to eliminate expensive wet etch operations.
    4. Polish (CMP) - To simplify the polish (CMP) operation, it is proposed that the bulk of the Cu be removed at the electroplater just after the completion of the electrodeposition. It is a straightforward process to reverse the polarity to make the wafer an anode and give (-) to the anode. This will dissolve the main affected part of the Cu and simplify the following operation - polish.
    Dec 28 2024 11:39:26 am
    Step 1 Etch Stop Deposition #
    (by (In development) Process Functional Modeling - New Process)

    1 Step is the transformation from the structure:


    To the structure:


    The Etch Stop layer is mainly needed to preserve the Cu diffusion to the ILD of the top layer - the top barrier. It is typically made of Si3N4 or SiC because increased density is needed to ensure barrier properties against Cu diffusion.

    The Etch Stop layer deposition is usually performed by the CVD method.

    The operation aims to create the Etch Stop layer therefore, the product is the "Etch Stop Layer"

    Operational Effectiveness – OE

    Effective

    Ineffective

    OE 1.51
    Operational Perfectness - OP

    Basic functions

    Components

    Supersystems

    OP 0.18
    Functional rank
    Problematic rank
    Plasma
    10
    CVD system
    5.5
    Initial layer
    4
    Gaseous Chemicals
    3.5
    Wafer
    3
    Cu - Initial layer
    2.5
    ILD - Initial layer
    2.5
    Chuck
    2
    Vacuum pump
    10
    By-product gases
    2.6
    Air
    9.2

    It is exciting results:

    Plasma is the most functional component - we have to think about plasma for effective improvement of the process

    The vacuum pump came out as the most problematic component of the system - we have to think about how to eliminate or replace the vacuum pump - Interesting.


    Overall:

    Etch stop Deposition is not a valuable operation. The operation's main purpose is to create a barrier between the Cu metal line and the top of ILD. Actually, we cover the surface of the wafer with Etch stop material, while we need it only on the top of Cu metal line.


    Maybe we need to think about the material that is adsorbed bu Cu only and is not adsorbed by SiO2 - ILD. The process could be done as follows: spinon liquid, removing the liquid from the wafer at high-speed rotation (the liquid should remain only on the metallic parts), and thermal treatment of the liquid to create a top barrier layer.


    So we need to develop a liquid that is adsorbed selectively by Cu and is converted to solid material after a thermal treatment.


    Possible example:

    A suitable liquid material that selectively adsorbs on Cu and converts to a solid after thermal treatment is Poly(methyl methacrylate) (PMMA) in a suitable solvent. Here’s how it works:

    Liquid Material: PMMA Solution

    1. Composition: PMMA can be dissolved in organic solvents such as toluene or acetone to create a liquid solution. The choice of solvent can influence the adsorption characteristics on Cu and SiO2.
    2. Selective Adsorption: PMMA has a higher affinity for Cu due to its ability to interact with the metal surface, while it exhibits lower adhesion to SiO2. This allows for selective adsorption on the Cu parts of the wafer.
    3. Thermal Treatment: Upon heating, the solvent evaporates, and the PMMA undergoes a polymerization process, leading to the formation of a solid PMMA film on the Cu areas. The thermal treatment can also help in cross-linking the PMMA, enhancing its mechanical properties.

    Process Steps:

    1. Spin Coating: Apply the PMMA solution onto the wafer and spin it to achieve a uniform layer. The centrifugal force will help remove excess material from the SiO2 areas.
    2. Thermal Treatment: After spin coating, subject the wafer to a thermal treatment (e.g., baking at around 100-150°C) to evaporate the solvent and convert the PMMA into a solid film.

    Advantages:

    1. Selective Adsorption: The liquid selectively adheres to Cu, allowing for precise patterning.
    2. Solid Film Formation: The conversion to a solid film provides structural integrity and can be further processed for various applications in semiconductor manufacturing.

    Considerations:

    1. Temperature Control: Ensure that the thermal treatment does not damage the underlying structures or materials on the wafer.
    2. Solvent Choice: The choice of solvent is crucial for achieving the desired selectivity and should be tested for compatibility with both Cu and SiO2 surfaces.

    This approach allows for effective selective adsorption and subsequent solidification, making it suitable for applications in wafer fabrication.


    Dec 28 2024 11:39:27 am
    Step 2 ILD Deposition #
    (by (In development) Process Functional Modeling - New Process)

    2 Step is the deposition of the ILD layer - a transformation from structure:

    To structure:


    ILD is typically built of SiO2 or modified SiO2 for the reduction of dielectric permittivity. The Electric permittivity reduction is typically achieved by the creation pores and dipping with C (in the form of methyl), Fluorine

    ILD deposition is typically made by the CVD process, where gaseous components are converted into a thin solid film due to the process in plasma.


    The operation aims to deposit ILD; therefore, the product (target) of the step is ILD.

    Operational Effectiveness – OE

    Effective

    Ineffective

    OE 2.57
    Operational Perfectness - OP

    Basic functions

    Components

    Supersystems

    OP 0.23
    Functional rank
    Problematic rank
    Plasma
    10
    Gaseous chemicals
    4
    Etch Stop layer
    4
    CVD Tool
    4
    Previous layers
    2.7
    Air residue
    2.7
    10
    Vacuum pump
    2
    2
    Wafer
    2
    Chuck
    1.3
    Gaseous by-products
    0.7

    Stupid question. Why do we need a vacuum for ILD deposition? I see only one possible reason - to create a free pathway that is long enough for plasma creation. OK. We need to think about how to ensure plasma and avoid deep vacuum. ILD that is SiO2 or modifications of SiO2 do not need a vacuum. More than that, the lack of oxygen

    Dec 28 2024 11:39:27 am
    Step 3 Sacrificial Layer Deposition for Via #
    (by (In development) Process Functional Modeling - New Process)

    3 Step is the deposition of the Sacrificial light-absorbing Layer (SLAL). The main purpose of this layer is to absorb the light during Photolithography and prevent the formation of a standing wave due to the interference of initial reflected light.

    The structure:



    Should be converted to the structure:


    The layer is typically deposited by a spin-on procedure similar to the deposition of a photoresist.


    The operation aims to deposit SLAL; therefore, the product (target) of the operation is SLAL.

    Operational Effectiveness – OE

    Effective

    Ineffective

    OE 1.35
    Operational Perfectness - OP

    Basic functions

    Components

    Supersystems

    OP 0.21
    Functional rank
    Problematic rank
    Chamber for Spin on
    10
    ILD layer
    5
    Furnace
    5
    Liquid material for Spin on deposition
    5
    Chuck
    4
    Air Fan
    4
    Air
    3
    Nozzle for liquid material
    3
    Wafer
    3
    Exhaust
    2
    Air Filter
    7.5
    Vapor of the liquid material
    10
    Vapors of solid sacrificial material
    10
    Particles
    5

    There are too many components. It would be easier and more effective to use hot air to solidify the Sacrificial Light Absorbing Material when it is on the wafer. So, the process seems to be like this: Wafer is kept in the chuck and rotated. The liquid stuff is poured on the rated wafer, and hot air solidifies the material on the wafer. The local flow of the air will preserve the wafer from the contamination of the layer. A chamber filter and Fan will not be needed.

    Dec 28 2024 11:39:27 am
    Step 4 Photolithography patterning for Via #
    (by (In development) Process Functional Modeling - New Process)

    4th Step is the wafer patterning using Photolithography (PL). PL is a preparation for the next step, which is Dry Etch (Plasma Etch). The purpose of the operation is to deposit the Photo Resist (PR) and create a pattern: the areas that are covered with the PR will not be affected by the Plasma etch, and opened areas will be etched by plasma.


    Incoming structure:


    Outcoming structure after the PL process should be as follows:



    This step creates the pattern for Via etch only. The PL process generally consists of three sequential parts: deposition of the Photo Resist (PR), Exposure - optical exposing of the PR through the special mask, and Development - chemical removal of the exposed part of the PR; unexposed parts will remain on the wafer. (In the case of "negative resist, "the effect is the opposite - exposed parts will remain, while unexposed parts will be removed at the development).


    The operation aims to create a patterned photoresist; therefore, its product (target) is Via Patterned PR.

    Operational Effectiveness – OE

    Effective

    Ineffective

    OE 4.01
    Operational Perfectness - OP

    Basic functions

    Components

    Supersystems

    OP 0.09
    Functional rank
    Problematic rank
    Exposed PR
    10
    10
    Liquid Developer
    10
    Scanner
    7.5
    Wafer
    5.8
    Oven
    5.8
    Liquid PR
    5.8
    5.8
    Sacrificial Light Absorbing Layer
    5
    5
    Solid PR
    4.2
    Development Chamber
    4.2
    Dev Nozzle
    4.2
    Exposure Chamber
    4.2
    Chuck for Spin on
    3.3
    Liquid PR layer
    3.3
    PR Spin on Chamber
    2.5
    Nozzle for liquid PR
    2.5
    Dev Chuck
    1.7
    Exposure Chuck
    1.7
    ILD layer
    1.7

    Photolithography does not add value to the product. The PL operation is very complex, so there is no reason to develop the operation and equipment. The PL operation is very expensive and must be simplified and eliminated.

    The Exposed Resist is the most functional component. So, let's document some ideas for simplification of the PL process:

    1. Why do we develop within the costly PL equipment? Developing the exposed resist is just a wet etch/clean process that can be performed with regular cheap wet cleaning equipment.
    2. Why do we need to develop exposed PR at all? Exposed PR is removed by an aqueous solution, this means that it can be removed by plasma. So, the idea is to apply plasma etch directly after exposure.
    Dec 28 2024 11:39:27 am
    Step 4 M - Critical Dimensions Measurements (CDM) - Via #
    (by (In development) Process Functional Modeling - New Process)

    Critical Dimensions Measurements (CDM) are performed after Photolithography. The main parameters of the photoresist pattern are measured and collected to decide whether to continue the wafer's process or return to the rework. The measurements are invasive, so they cannot be done on the die; they are performed on the scribe line between the dies on the specially created metro cell. Every single measurement is performed on the new metro cell because the measurements destroy the metro cell. The fragment of the typical pattern is shown below.


    The main purpose of the CDM operation is the information, Product is Information.

    Operational Effectiveness – OE

    Effective

    Ineffective

    OE 1.9
    Operational Perfectness - OP

    Basic functions

    Components

    Supersystems

    Functional rank
    Problematic rank
    Metrology tool
    10
    10
    Patterned Photoresist
    4
    Metro Cell
    3
    Wafer
    2

    The operation does not increase the product's value and only gives data to decide on the necessity of rework. The best way is to analyze the statistics and insert a reasonable skip of the operation. The criteria should be the ratio: "Gain/Cost" .

    Dec 28 2024 11:39:27 am
    Step 5 Via Etch #
    (by (In development) Process Functional Modeling - New Process)

    5th Step is to etch a Via according to the pattern that was made at the previous step - Via Photo Lithography. The etch is performed with plasma on the all surface of the wafer. The open parts will be etched, while the parts that are covered with the Photoresist (PR) will remain unchanged. The wafer is placed on the chuck, kept with static electricity and treated with plasma containing the ions and/or radicals to be able to convert the ILD in to the gas. Typically, the plasma contains fluorine that converts silicon oxide to gaseous silicon tetrafluoride.

    Incoming structure:


    Outcoming structure:


    This step is a productive operation that provides irreversible changes and increases the value of the product.


    The operation aims to create a Via within the ILD according to the patterned resist on the wafer. A via is created due to the conversion of SiO2 of ILD into gaseous SiF4, therefore, its product (target) is a SiF4 - gas.

    Operational Effectiveness – OE

    Effective

    Ineffective

    OE 2.88
    Operational Perfectness - OP

    Basic functions

    Components

    Supersystems

    OP 0.44
    Functional rank
    Problematic rank
    Fluorine ions
    10
    Etch stop Layer
    8.9
    Plasma
    6.7
    3.9
    ILD
    6.7
    Pump
    5.6
    10
    Photoresist
    5.6
    Electromagnetic field
    5.6
    Sacrificial light absorbing layer
    2.2
    1.7
    Residual gases
    2.2

    The vacuum pump seems to be the most problematic component of the system. The pump is used to create a vacuum in the chamber to ensure a long enough free path for the ions and radicles. At the same time, the pump should remove the etch product - SiF4 gas. The problem is the SiF4 gas may not be removed effectively because of the high vacuum. Excessing SiF4 reduces the etch rate and can result in the under etch. SiF4 and other gaseous by-products should be pumped out properly and fast to ensure a high and stable etch rate of the process.

    One of the possible solutions that came out of the 40 Inventive Principles analysis is to make the Dry etch process in pulses to allow better pumping out of the SiF4 and all other gaseous by-products.

    Dec 28 2024 11:39:27 am
    Step 6 Wet Cleaning after Via Etch #
    (by (In development) Process Functional Modeling - New Process)

    Wet cleaning is typically performed after the Dry etch process to remove the residual photoresist and sacrificial light-absorbing material and to clean the via from the by-products formed during the Dry etch process—the interaction of plasma with pattern and ILD.

    The incoming structure is shown below:


    The outcoming structure should look as follows:


    The purpose of the operation is to remove the temporary pattern. So, the product (target) of the operation Residue.

    Operational Effectiveness – OE

    Effective

    Ineffective

    OE 2.4
    Operational Perfectness - OP

    Basic functions

    Components

    Supersystems

    OP 0.18
    Functional rank
    Problematic rank
    Cleaning solution
    10
    10
    Chuck
    7.5
    Wet Cleaning system
    5
    Dissolved Residue
    5
    2.5
    Nozzle
    2.5

    It is interesting that "Chuck" becomes a component with relatively high functionality. It occurs because it is important to dissolve the residue, but we also need to remove the dissolved residue; otherwise, the residue will remain on the wafer. The removal of the dissolved residue becomes very important.


    From 40 inventive principles, we generated an idea to invert the process. Instead of pouring the chemistry on the rotating wafer, we can dip the rotating wafer face down into the solution in the bath.


    Another direction for development and real innovation is to remove the residue at the previous operation - dry etch. In this case, the Wet etch operation will not be necessary and can be eliminated.

    Dec 28 2024 11:39:27 am
    Step 7 Sacrificial Layer Deposition for Trench #
    (by (In development) Process Functional Modeling - New Process)

    The seventh step is depositing the Sacrificial light-absorbing Layer (SLAL). This layer has two purposes: to fill in the via and avoid unnecessary etching within it, to absorb light during photolithography, and to prevent the formation of a standing wave due to the interference of initial reflected light.


    The initial structure:




    Should be converted to the structure:



    The layer is typically deposited by a spin-on procedure similar to the deposition of a photoresist.


    The operation aims to deposit SLAL; therefore, the product (target) of the operation is SLAL.

    Operational Effectiveness – OE

    Effective

    Ineffective

    OE 1.35
    Operational Perfectness - OP

    Basic functions

    Components

    Supersystems

    OP 0.21
    Functional rank
    Problematic rank
    Chamber for Spin on
    10
    ILD layer
    5
    Furnace
    5
    Liquid material for Spin on deposition
    5
    Chuck
    4
    Air Fan
    4
    Air
    3
    Nozzle for liquid material
    3
    Wafer
    3
    Exhaust
    2
    Air Filter
    7.5
    Vapor of the liquid material
    10
    Vapors of solid sacrificial material
    10
    Particles
    5

    Same as the Step 3 - Sacrificial Layer Deposition for Via

    There are too many components. It would be easier and more effective to use hot air to solidify the Sacrificial LigLight-Absorbing Material the wafer. So, the process seems to be like this: WafThe wafer is kept in the chuck and rotated. The liquid is poured onto a rated wafer, and hot air solidifies the material on the wafer. The local flow of the air will preserve the wafer from contamination by layer. A chamber filter and Fan will not be needed.

    Dec 28 2024 11:39:27 am
    Step 8 Photolithography Patterning for Trench #
    (by (In development) Process Functional Modeling - New Process)

    The eighth 8 step is wafer patterning using Photolithography (PL). PL prepares the wafer for the next step, Dry Etch (Plasma Etch). The operation deposits the Photo Resist (PR) and creates a pattern: areas covered with PR are not affected by the Plasma etch, and opened areas are etched by plasma. This operation is for Trench patterning.


    Incoming structure:


    Outcoming structure after the PL process should be as follows:



    This step creates the pattern for Trench etch only. The PL process generally consists of three sequential parts: deposition of the Photo Resist (PR), Exposure - optical exposing of the PR through the special mask, and Development - chemical removal of the exposed part of the PR; unexposed parts will remain on the wafer. (In the case of "negative resist, "the effect is the opposite - exposed parts will remain, while unexposed parts will be removed at the development).


    The operation aims to create a patterned photoresist, so its product (target) is Trench-Patterned PR.

    Operational Effectiveness – OE

    Effective

    Ineffective

    OE 4.01
    Operational Perfectness - OP

    Basic functions

    Components

    Supersystems

    OP 0.09
    Functional rank
    Problematic rank
    Exposed PR
    10
    10
    Liquid Developer
    10
    Scanner
    7.5
    Wafer
    5.8
    Oven
    5.8
    Liquid PR
    5.8
    5.8
    Sacrificial Light Absorbing Layer
    5
    5
    Solid PR
    4.2
    Development Chamber
    4.2
    Dev Nozzle
    4.2
    Exposure Chamber
    4.2
    Chuck for Spin on
    3.3
    Liquid PR layer
    3.3
    PR Spin on Chamber
    2.5
    Nozzle for liquid PR
    2.5
    Dev Chuck
    1.7
    Exposure Chuck
    1.7
    ILD layer
    1.7

    Photolithography does not add value to the product. The PL operation is very complex, so there is no reason to develop the operation and equipment. The PL operation is very expensive and must be simplified and eliminated.

    The Exposed Resist is the most functional component. So, let's document some ideas for simplification of the PL process:

    1. Why do we develop within the costly PL equipment? Developing the exposed resist is just a wet etch/clean process that can be performed with regular cheap wet cleaning equipment.
    2. Why do we need to develop exposed PR at all? Exposed PR is removed by an aqueous solution, this means that it can be removed by plasma. So, the idea is to apply plasma etch directly after exposure.
    Dec 28 2024 11:39:27 am
    Step 8 M - Critical Dimensions Measurements (CDM) - Trench #
    (by (In development) Process Functional Modeling - New Process)

    Critical Dimensions Measurements (CDM) are performed after Photolithography. The main parameters of the photoresist pattern are measured and collected to decide whether to continue the wafer's process or return to the rework. Because the measurements are invasive, they cannot be performed on the die; they are performed on the scribe line between the dies on the specially created metro cell. Every single measurement is performed on the new metro cell because they destroy the metro cell. The fragment of the typical pattern is shown below.


    The structure that is submitted to CDM:



    The main purpose of the CDM operation is the information, Product is Information.

    Operational Effectiveness – OE

    Effective

    Ineffective

    OE 1.9
    Operational Perfectness - OP

    Basic functions

    Components

    Supersystems

    Functional rank
    Problematic rank
    Metrology tool
    10
    10
    Patterned Photoresist
    4
    Metro Cell
    3
    Wafer
    2

    The operation does not increase the product's value and only gives data to decide on the necessity of rework. The best way is to analyze the statistics and insert a reasonable skip of the operation. The criteria should be the ratio: "Gain/Cost" .

    Dec 28 2024 11:39:27 am
    Step 9 Trench Etch for Metal Line #
    (by (In development) Process Functional Modeling - New Process)

    9th Step is to etch a Trench for metal wires according to the pattern made at the previous step - Trench Photo Lithography. The etch is performed with plasma on the complete surface of the wafer. The open parts will be etched, while the parts covered with the Photoresist (PR) will remain unchanged. The wafer is placed on the chuck, kept with static electricity and treated with plasma containing the ions and/or radicals to be able to convert the ILD in to the gas. Typically, the plasma contains fluorine that converts silicon oxide to gaseous silicon tetrafluoride.

    Incoming structure:



    Outcoming structure:




    This step is a productive operation that provides irreversible changes and increases the value of the product.


    The operation aims to create a Via within the ILD according to the patterned resist on the wafer. A via is created due to the conversion of SiO2 of ILD into gaseous SiF4; therefore, its product (target) is a SiF4 - gas.

    Operational Effectiveness – OE

    Effective

    Ineffective

    OE 2.88
    Operational Perfectness - OP

    Basic functions

    Components

    Supersystems

    OP 0.44
    Functional rank
    Problematic rank
    Fluorine ions
    10
    Etch stop Layer
    8.9
    Plasma
    6.7
    3.9
    ILD
    6.7
    Pump
    5.6
    10
    Photoresist
    5.6
    Electromagnetic field
    5.6
    Sacrificial light absorbing layer
    2.2
    1.7
    Residual gases
    2.2

    The vacuum pump seems to be the most problematic component of the system. The pump is used to create a vacuum in the chamber to ensure a long enough free path for the ions and radicles. At the same time, the pump should remove the etch product - SiF4 gas. The problem is the SiF4 gas may not be removed effectively because of the high vacuum. Excessing SiF4 reduces the etch rate and can result in the under etch. SiF4 and other gaseous by-products should be pumped out properly and fast to ensure a high and stable etch rate of the process.

    One of the possible solutions that came out of the 40 Inventive Principles analysis is to make the Dry etch process in pulses to allow better pumping out of the SiF4 and all other gaseous by-products.

    Dec 28 2024 11:39:27 am
    Step 10 Wet Cleaning after Trench Etch #
    (by (In development) Process Functional Modeling - New Process)

    Wet cleaning is typically performed after the Dry etch process to remove the residual photoresist and sacrificial light-absorbing material and to clean the via from the by-products formed during the Dry etch process—the interaction of plasma with pattern and ILD.

    The incoming structure is shown below:



    The outcoming structure should look as follows:



    The purpose of the operation is to remove the temporary pattern. So, the product (target) of the operation Residue.

    Operational Effectiveness – OE

    Effective

    Ineffective

    OE 2.4
    Operational Perfectness - OP

    Basic functions

    Components

    Supersystems

    OP 0.18
    Functional rank
    Problematic rank
    Cleaning solution
    10
    10
    Chuck
    7.5
    Wet Cleaning system
    5
    Dissolved Residue
    5
    2.5
    Nozzle
    2.5

    It is interesting that "Chuck" becomes a component with relatively high functionality. It occurs because it is important to dissolve the residue, but we also need to remove the dissolved residue; otherwise, the residue will remain on the wafer. The removal of the dissolved residue becomes very important.


    From 40 inventive principles, we generated an idea to invert the process. Instead of pouring the chemistry on the rotating wafer, we can dip the rotating wafer face down into the solution in the bath.


    Another direction for development and real innovation is to remove the residue at the previous operation - dry etch. In this case, the Wet etch operation will not be necessary and can be eliminated.

    Dec 28 2024 11:39:27 am
    Step 11 Ta-Barrier + Cu-Seed layers Deposition #
    (by (In development) Process Functional Modeling - New Process)

    Step 11 is dedicated to depositing a thin layer of Tantalum (Ta) metal. Ta layer aims to prevent diffusion of copper (Cu) in the ILD, which is a silico-oxide-based dielectric material. Ta layer is a barrier between ILD and Cu. The operation's next step is disposing of a thin layer of Cu. This thin Cu layer aims to enable an electrical contact at the next operation - that is, electroplating - bulk Cu deposition by electrolysis. This thin Cu layer is named the Cu-seed layer because it allows the connection of the wafer to the Cathode and the electroplating process. Both Ta-barrier and Cu-seed layers are deposited using the PVD process - Physical Vapour Deposition. The plasma ions and radicles attract the target, which is made of relevant material - either Ta or Cu. The liberated metal aglomerates are deposited on the wafer surface, including the structure walls - vias and trenches of the metal lines.


    The incoming structure is shown below:




    The outcoming structure is shown below - Ta-barrier and Cu-seed layers are shown as a single black line:


    The purpose of the operation is to deposit a Ta-barrier and Cu-seed layer. The Cu-seed layer is deposited on the top of the Ta-barrier layer; therefore, we can assign the Cu-seed layer as a product (target) of the operation.

    Operational Effectiveness – OE

    Effective

    Ineffective

    OE 2.47
    Operational Perfectness - OP

    Basic functions

    Components

    Supersystems

    OP 0.2
    Functional rank
    Problematic rank
    Ions & radicles
    10
    4.4
    Electromagnetic field
    7.5
    Ta - barrier layer
    5
    Cu agglomerates
    3.1
    Wafer
    3.1
    Ta agglomerates
    1.9
    Process gas
    1.9
    Cu - target
    1.9
    Ta - target
    1.3
    Chuck
    1.3
    Vacuum pump
    1.3
    1.1
    Air
    10

    Step 11 is dedicated to the Ta-barrier and Cu-seed deposition. This operation is defined as a Productive operation that is right and not right. The main part of the deposited Ta-Barrier and Cu-seed is removed anyway. Therefore, it would be more correct to define this operation as Providing. The best way is to split this operation into two: Barrier deposition and Seed deposition. Such an approach will help us to think differently and enhance or eliminate these operations separately.

    Dec 28 2024 11:39:27 am
    Step 11 M - Defects Detection & Measurements #
    (by (In development) Process Functional Modeling - New Process)

    Defect detection and measurements are typically performed after the Ta-barrier and Cu-seed layer deposition. There are several reasons for the defect metrology after this operation. First, the wafer is in a safe condition - the wafer is covered with a thin layer of Cu that prevents the wafer materials from oxidation by outside air. Second, the conductive thin layer ensures the defects' visibility and prevents the wafer surface's charging. The defects metrology is added to the process to ensure that the operations are completed as per requirements, the equipment operates correctly, and wafers can be released to the next operation.

    The fragment of the typical pattern is shown below.


    The structure that is submitted to defect metrology operation:




    The main purpose of the defect metrology operation is information, and the product is information.

    Operational Effectiveness – OE

    Effective

    Ineffective

    OE 2.29
    Operational Perfectness - OP

    Basic functions

    Components

    Supersystems

    Functional rank
    Problematic rank
    Metrology tool
    10
    10
    Cu-seed layer
    5.7
    Die
    4.3
    Wafer
    2.9

    The operation does not increase the product's value and only gives data to decide on the necessity of rework. The best way is to analyze the statistics and insert a reasonable skip of the operation. The criteria should be the ratio: "Gain/Cost" .

    Dec 28 2024 11:39:27 am
    Step 12 Cu Electroplating #
    (by (In development) Process Functional Modeling - New Process)

    Step 12 - Cu electroplating is the operation that aims to fill in the bulk copper (Cu). The wafer is processed using electroplating equipment. The wafer is connected to the cathode (-) and placed in the electrolyte containing dissolved Cu- sulfate, CuSO4 and sulfuric acid. The anode is made of pure copper, Cu. During the process, the wafer rotates to enhance the diffusion process while the delivery of Cu-ions to the surface of the wafer. The process is performed as regular electroplating: Cu is dissolved on the anode (+) by losing electrons and forming Cu(2+) ions. Cu(2+) ions are reduced on the cathode by accepting electrons to Cu atoms that are deposited in the form of a Cu-metal layer on the surface of the wafer.

    The main challenge is the formation of voids within the deposited Cu layer. The reasons for the void formation are as follows:

    1. Bubble formation: H(+) discharge and formation of H2 bubbles. This typically occurs when the voltage is too high, which results from improper electrical contact, the Cu-seed layer not being thick enough, etc.
    2. Bubbles remaining: Air should be completely replaced by the electrolyte, but if air bubbles remain encapsulated by the electrolyte and Cu deposit
    3. Electrolyte drops: the electrolyte should be completely replaced by the Cu that is electroplated during the process, but the growing Cu deposit can encapsulate some drops of the electrolyte.

    The deposition is always above the required level to ensure that the bubbles and some defects are mainly concentrated in the top part of the deposit and will be removed at the next operation.


    The incoming structure is shown below:


    The outcoming structure is shown here:


    The purpose of the operation is to plate the Cu, so the product is Electroplated Cu

    Operational Effectiveness – OE

    Effective

    Ineffective

    OE 1.65
    Operational Perfectness - OP

    Basic functions

    Components

    Supersystems

    OP 0.07
    Functional rank
    Problematic rank
    Electricity
    10
    3.1
    Electrolyte
    5
    10
    Cu(2+) ions
    4.4
    Cu Anode
    3.1
    Air
    2.5
    0.8
    Chuck
    2.5
    Cu-seed layer
    2.5
    Electric connection to anode
    2.5
    0.3
    DC Power supply
    2.5
    Wafer
    1.9
    3.7
    Electric connection to wafer (cathode)
    1.3
    0.3
    H(+) iones
    0.5
    Air bubbles
    1.5
    H2 bubbles
    1.5
    Electrolyte drops
    1.5

    The electrolyte seems to be the most functional and problematic component of the system. The main problem is eliminating the remaining air bubbles. The first step to improving this operation is reducing surface tension to ensure the electrolyte penetrates all the structures.

    Dec 28 2024 11:39:27 am
    Step 13 Excessive Cu and Barrier Removal by Polish #
    (by (In development) Process Functional Modeling - New Process)

    Step 13 - Excessive Cu and Ta-barrier removal by polish aims to remove all metal parts that make contact between different metal lines that should not be connected. The operation is performed using the chemical-mechanical polishing (CMP) method.

    The wafer is kept in the holder and pushed face down to the pad. A slurry containing fumed silica or other relevant material is poured on the pad to ensure the material is removed by polishing. A special conditioner cleans the pad from the residual material created during the polishing. The very general scheme of the polisher is shown below (taken from the Wikipedia):


    The incoming structure is shown below:



    The outcoming structure is shown here:



    The purpose of the operation is to remove the excessive material - Cu, Ta, ILD. The operation's product is excessive material.

    Operational Effectiveness – OE

    Effective

    Ineffective

    OE 1.38
    Operational Perfectness - OP

    Basic functions

    Components

    Supersystems

    OP 0.27
    Functional rank
    Problematic rank
    Pad
    10
    10
    Slurry
    8
    8
    Excessive material on the wafer
    6
    6
    Excessive material on the pad
    4
    Wafer holder
    2
    Wafer
    2
    DI Water
    2
    2
    Conditioner
    2

    Step 13 - Excessive Cu and Ta Barrier layer removal by polish is a corrective operation - no value is added. The operation exists because of the problematic previous operation. The excessive Cu is deposited to ensure that all defects and voids generated during the electroplating are collected in the excessive part of the deposit and can be removed at the polish.

    Since the Polish is a corrective operation, it does not make any sense to improve or develop such an operation. The correct direction is to work on eliminating or simplifying the operation. For instance, it would be reasonable to remove the bulk of the Cu at the electroplater just after the completion of the electrodeposition. It is very easy process just to replace the polarity to make the wafer an anode and give (-) to the anode. It will dissolve the main affected part of the Cu and simplify the following operation - polish.

    Dec 28 2024 11:39:27 am
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